guest ::
| Home > Publications database > Symmetry-resolved CO desorption and oxidation dynamics on O/Ru(0001) probed at the C K-edge by ultrafast x-ray spectroscopy > print |
| Home > Publications database > Symmetry-resolved CO desorption and oxidation dynamics on O/Ru(0001) probed at the C K-edge by ultrafast x-ray spectroscopy > print |
| 001 | 483446 | ||
| 005 | 20250715175841.0 | ||
| 024 | 7 | _ | |a 10.1063/5.0114399 |2 doi |
| 024 | 7 | _ | |a 0021-9606 |2 ISSN |
| 024 | 7 | _ | |a 1089-7690 |2 ISSN |
| 024 | 7 | _ | |a 1520-9032 |2 ISSN |
| 024 | 7 | _ | |a 10.3204/PUBDB-2022-05333 |2 datacite_doi |
| 024 | 7 | _ | |a altmetric:136741460 |2 altmetric |
| 024 | 7 | _ | |a 36319417 |2 pmid |
| 024 | 7 | _ | |a WOS:000876502600007 |2 WOS |
| 024 | 7 | _ | |2 openalex |a openalex:W4297932591 |
| 037 | _ | _ | |a PUBDB-2022-05333 |
| 082 | _ | _ | |a 530 |
| 100 | 1 | _ | |a LaRue, Jerry |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Symmetry-resolved CO desorption and oxidation dynamics on O/Ru(0001) probed at the C K-edge by ultrafast x-ray spectroscopy |
| 260 | _ | _ | |a Melville, NY |c 2022 |b American Institute of Physics |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1667303251_15760 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a We report on carbon monoxide desorption and oxidation induced by 400 nm femtosecond laser excitation on the O/Ru(0001) surface probed by time-resolved x-ray absorption spectroscopy (TR-XAS) at the carbon K-edge. The experiments were performed under constant background pressures of CO (6 × 10$^{−8}$ Torr) and O$_2$ (3 × 10$^{−8}$ Torr). Under these conditions, we detect two transient CO species with narrow 2$π^*$ peaks, suggesting little 2π* interaction with the surface. Based on polarization measurements, we find that these two species have opposing orientations: (1) CO favoring a more perpendicular orientation and (2) CO favoring a more parallel orientation with respect to the surface. We also directly detect gas-phase CO2 using a mass spectrometer and observe weak signatures of bent adsorbed CO2 at slightly higher x-ray energies than the 2$π^*$ region. These results are compared to previously reported TR-XAS results at the O K-edge, where the CO background pressure was three times lower (2 × 10$^{−8}$ Torr) while maintaining the same O$_2$ pressure. At the lower CO pressure, in the CO 2$π^*$ region, we observed adsorbed CO and a distribution of OC–O bond lengths close to the CO oxidation transition state, with little indication of gas-like CO. The shift toward “gas-like” CO species may be explained by the higher CO exposure, which blocks O adsorption, decreasing O coverage and increasing CO coverage. These effects decrease the CO desorption barrier through dipole–dipole interaction while simultaneously increasing the CO oxidation barrier. |
| 536 | _ | _ | |a 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) |0 G:(DE-HGF)POF4-632 |c POF4-632 |f POF IV |x 0 |
| 536 | _ | _ | |a VH-NG-1105 - Novel soft X-ray spectroscopies for materials science (2016_IVF-VH-NG-1105) |0 G:(DE-HGF)2016_IVF-VH-NG-1105 |c 2016_IVF-VH-NG-1105 |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
| 693 | _ | _ | |0 EXP:(DE-MLZ)External-20140101 |5 EXP:(DE-MLZ)External-20140101 |e Measurement at external facility |x 0 |
| 700 | 1 | _ | |a Liu, Boyang |b 1 |
| 700 | 1 | _ | |a Rodrigues, Gabriel L. S. |0 0000-0002-6580-3336 |b 2 |
| 700 | 1 | _ | |a Liu, Chang |b 3 |
| 700 | 1 | _ | |a Garrido Torres, Jose Antonio |b 4 |
| 700 | 1 | _ | |a Schreck, Simon |b 5 |
| 700 | 1 | _ | |a Diesen, Elias |0 0000-0002-8235-3920 |b 6 |
| 700 | 1 | _ | |a Weston, Matthew |b 7 |
| 700 | 1 | _ | |a Ogasawara, Hirohito |b 8 |
| 700 | 1 | _ | |a Perakis, Fivos |0 0000-0001-9863-9811 |b 9 |
| 700 | 1 | _ | |a Dell’Angela, Martina |0 0000-0003-1228-2458 |b 10 |
| 700 | 1 | _ | |a Capotondi, Flavio |b 11 |
| 700 | 1 | _ | |a Ball, Devon |b 12 |
| 700 | 1 | _ | |a Carnahan, Conner |b 13 |
| 700 | 1 | _ | |a Zeri, Gary |b 14 |
| 700 | 1 | _ | |a Giannessi, Luca |b 15 |
| 700 | 1 | _ | |a Pedersoli, Emanuele |b 16 |
| 700 | 1 | _ | |a Naumenko, Denys |b 17 |
| 700 | 1 | _ | |a Amann, Peter |b 18 |
| 700 | 1 | _ | |a Nikolov, Ivaylo |b 19 |
| 700 | 1 | _ | |a Raimondi, Lorenzo |b 20 |
| 700 | 1 | _ | |a Spezzani, Carlo |b 21 |
| 700 | 1 | _ | |a Beye, Martin |0 P:(DE-H253)PIP1005334 |b 22 |
| 700 | 1 | _ | |a Voss, Johannes |b 23 |
| 700 | 1 | _ | |a Wang, Hsin-Yi |b 24 |
| 700 | 1 | _ | |a Cavalca, Filippo |b 25 |
| 700 | 1 | _ | |a Gladh, Jörgen |0 P:(DE-H253)PIP1084379 |b 26 |
| 700 | 1 | _ | |a Koroidov, Sergey |b 27 |
| 700 | 1 | _ | |a Abild-Pedersen, Frank |b 28 |
| 700 | 1 | _ | |a Kolb, Manuel |b 29 |
| 700 | 1 | _ | |a Miedema, Piter S. |0 P:(DE-H253)PIP1032830 |b 30 |
| 700 | 1 | _ | |a Costantini, Roberto |b 31 |
| 700 | 1 | _ | |a Heinz, Tony F. |b 32 |
| 700 | 1 | _ | |a Luntz, Alan C. |b 33 |
| 700 | 1 | _ | |a Pettersson, Lars G. M. |b 34 |
| 700 | 1 | _ | |a Nilsson, Anders |b 35 |
| 773 | _ | _ | |a 10.1063/5.0114399 |g Vol. 157, no. 16, p. 164705 - |0 PERI:(DE-600)1473050-9 |n 16 |p 164705 |t The journal of chemical physics |v 157 |y 2022 |x 0021-9606 |
| 856 | 4 | _ | |y Published on 2022-10-25. Available in OpenAccess from 2023-10-25. |u https://bib-pubdb1.desy.de/record/483446/files/5.0114399.pdf |
| 856 | 4 | _ | |y Published on 2022-10-25. Available in OpenAccess from 2023-10-25. |u https://bib-pubdb1.desy.de/record/483446/files/Accepted%20manuscript.pdf |
| 856 | 4 | _ | |y Published on 2022-10-25. Available in OpenAccess from 2023-10-25. |x pdfa |u https://bib-pubdb1.desy.de/record/483446/files/Accepted%20manuscript.pdf?subformat=pdfa |
| 856 | 4 | _ | |y Published on 2022-10-25. Available in OpenAccess from 2023-10-25. |x pdfa |u https://bib-pubdb1.desy.de/record/483446/files/5.0114399.pdf?subformat=pdfa |
| 909 | C | O | |o oai:bib-pubdb1.desy.de:483446 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 22 |6 P:(DE-H253)PIP1005334 |
| 910 | 1 | _ | |a European XFEL |0 I:(DE-588)1043621512 |k XFEL.EU |b 22 |6 P:(DE-H253)PIP1005334 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 26 |6 P:(DE-H253)PIP1084379 |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 30 |6 P:(DE-H253)PIP1032830 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 30 |6 P:(DE-H253)PIP1032830 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l From Matter to Materials and Life |1 G:(DE-HGF)POF4-630 |0 G:(DE-HGF)POF4-632 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Materials – Quantum, Complex and Functional Materials |x 0 |
| 914 | 1 | _ | |y 2022 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2021-02-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2021-02-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |d 2021-02-02 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2021-02-02 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2021-02-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2021-02-02 |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |d 2021-02-02 |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |d 2021-02-02 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b J CHEM PHYS : 2019 |d 2021-02-02 |
| 915 | _ | _ | |a National-Konsortium |0 StatID:(DE-HGF)0430 |2 StatID |d 2021-02-02 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2021-02-02 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0320 |2 StatID |b PubMed Central |d 2021-02-02 |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |d 2021-02-02 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2021-02-02 |
| 920 | 1 | _ | |0 I:(DE-H253)FS-FLASH-20140814 |k FS-FLASH |l FS-FLASH |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-H253)FS-FLASH-20140814 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|