TY - JOUR
AU - Bon, Volodymyr
AU - Busov, Nikita
AU - Senkovska, Irena
AU - Bönisch, Nadine
AU - Abylgazina, Leila
AU - Khadiev, Azat
AU - Novikov, Dmitri
AU - Kaskel, Stefan
TI - The importance of crystal size for breathing kinetics in MIL-53(Al)
JO - Chemical communications
VL - 58
IS - 75
SN - 0009-241X
CY - Cambridge
PB - Soc.
M1 - PUBDB-2022-04630
SP - 10492 - 10495
PY - 2022
AB - Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al).
LB - PUB:(DE-HGF)16
C6 - 36043355
UR - <Go to ISI:>//WOS:000847697800001
DO - DOI:10.1039/D2CC02662G
UR - https://bib-pubdb1.desy.de/record/481937
ER -