000481932 001__ 481932 000481932 005__ 20250715175418.0 000481932 0247_ $$2doi$$a10.3389/femat.2022.837651 000481932 0247_ $$2datacite_doi$$a10.3204/PUBDB-2022-04625 000481932 0247_ $$2altmetric$$aaltmetric:83450146 000481932 0247_ $$2openalex$$aopenalex:W4214818317 000481932 037__ $$aPUBDB-2022-04625 000481932 041__ $$aEnglish 000481932 082__ $$a540 000481932 1001_ $$0P:(DE-H253)PIP1094159$$aGrockowiak, Audrey$$b0$$eCorresponding author 000481932 245__ $$aHot Hydride Superconductivity Above 550 K 000481932 260__ $$aLausanne$$bFrontiers Media$$c2022 000481932 3367_ $$2DRIVER$$aarticle 000481932 3367_ $$2DataCite$$aOutput Types/Journal article 000481932 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1672754606_4912 000481932 3367_ $$2BibTeX$$aARTICLE 000481932 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000481932 3367_ $$00$$2EndNote$$aJournal Article 000481932 520__ $$aThe search for room temperature superconductivity has accelerated in the last few years driven by experimentally accessible theoretical predictions that indicated alloying dense hydrogen with other elements could produce conventional superconductivity at high temperatures and pressures. These predictions helped inform the synthesis of simple binary hydrides that culminated in the discovery of the superhydride LaH10 with a superconducting transition temperature Tc of 260 K at 180 GPa. We have now successfully synthesized a metallic La-based superhydride with an initial Tc of 294 K. When subjected to subsequent thermal excursions that promoted a chemical reaction to a higher order system, the Tc onset was driven irreversibly to 556 K. X-ray characterization confirmed the formation of a distorted LaH10 based backbone that suggests the formation of ternary or quaternary compounds with substitution at the La and/or H sites. The results provide evidence for hot superconductivity, aligning with recent predictions for higher order hydrides under pressure. 000481932 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x0 000481932 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x1 000481932 588__ $$aDataset connected to DataCite 000481932 693__ $$0EXP:(DE-H253)P-P02.2-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P02.2-20150101$$aPETRA III$$fPETRA Beamline P02.2$$x0 000481932 7001_ $$0P:(DE-HGF)0$$aAhart, Muhtar$$b1 000481932 7001_ $$0P:(DE-HGF)0$$aHelm, Toni$$b2 000481932 7001_ $$0P:(DE-HGF)0$$aConiglio, W. 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