000480968 001__ 480968
000480968 005__ 20250724151616.0
000480968 0247_ $$2doi$$a10.1039/D2TA00078D
000480968 0247_ $$2ISSN$$a2050-7488
000480968 0247_ $$2ISSN$$a2050-7496
000480968 0247_ $$2datacite_doi$$a10.3204/PUBDB-2022-04108
000480968 0247_ $$2altmetric$$aaltmetric:125463773
000480968 0247_ $$2WOS$$aWOS:000779385800001
000480968 0247_ $$2openalex$$aopenalex:W4220880692
000480968 037__ $$aPUBDB-2022-04108
000480968 041__ $$aEnglish
000480968 082__ $$a530
000480968 1001_ $$aFang, Yuan$$b0
000480968 245__ $$aLithium insertion in hard carbon as observed by $^7$Li NMR and XRD. The local and mesoscopic order and their relevance for lithium storage and diffusion
000480968 260__ $$aLondon ˜[u.a.]œ$$bRSC$$c2022
000480968 3367_ $$2DRIVER$$aarticle
000480968 3367_ $$2DataCite$$aOutput Types/Journal article
000480968 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1659517095_20238
000480968 3367_ $$2BibTeX$$aARTICLE
000480968 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000480968 3367_ $$00$$2EndNote$$aJournal Article
000480968 520__ $$aWe investigate hard carbon fibers in different states of charge by a combination of $^7$Li-NMR and 2D-XRD. In particular, we record the quadrupole-split $^7$Li-NMR spectra and $^7$Li longitudinal relaxation over a wide temperature range, and determine lithium self-diffusion both parallel and perpendicular to the fiber axis. Recording the temperature dependence permits us to interpret the presence of motional averaging of spin couplings for mobile Li. The joint analysis shows that at low Li content, Li occupies sites that lack ordered coordination and delocalized electrons and are collected in disordered spatial domains. Upon increasing the Li content, ordered sites collected in ordered domains become populated. Both disordered and ordered domains have a high inherent heterogeneity with a typical spatial extension of a few nanometers. The disordered domains exhibit a continuous topology that permits unhindered diffusion within it. At high Li content we also observe the presence of very small (∼nm) particles of metallic lithium. The joint analysis of XRD in combination with diffusion anisotropy, and anisotropy from the $^7$Li-NMR spectrum (with samples oriented differently with regard to the applied magnetic field), shows that the mesoscopic structure is made by ordered domains arranged in a cylindrically rolled-up manner with the mesoscopic axis parallel to the fiber axis.
000480968 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x0
000480968 536__ $$0G:(DE-H253)I-20210412-EC$$aFS-Proposal: I-20210412 EC (I-20210412-EC)$$cI-20210412-EC$$x1
000480968 536__ $$0G:(DE-H253)I-20190372-EC$$aFS-Proposal: I-20190372 EC (I-20190372-EC)$$cI-20190372-EC$$x2
000480968 536__ $$0G:(DE-H253)I-20190548-EC$$aFS-Proposal: I-20190548 EC (I-20190548-EC)$$cI-20190548-EC$$x3
000480968 536__ $$0G:(DE-HGF)2020_Join2-SWEDEN-DESY$$aSWEDEN-DESY - SWEDEN-DESY Collaboration (2020_Join2-SWEDEN-DESY)$$c2020_Join2-SWEDEN-DESY$$x4
000480968 588__ $$aDataset connected to DataCite
000480968 693__ $$0EXP:(DE-H253)P-P03-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P03-20150101$$aPETRA III$$fPETRA Beamline P03$$x0
000480968 7001_ $$0P:(DE-H253)PIP1090762$$aPeuvot, Kevin$$b1
000480968 7001_ $$0P:(DE-H253)PIP1083991$$aGratrex, Alice$$b2
000480968 7001_ $$aMorozov, Evgeny V.$$b3
000480968 7001_ $$0P:(DE-H253)PIP1032169$$aHagberg, Johan$$b4
000480968 7001_ $$0P:(DE-H253)PIP1087875$$aLindbergh, Göran$$b5
000480968 7001_ $$0P:(DE-HGF)0$$aFuró, István$$b6$$eCorresponding author
000480968 773__ $$0PERI:(DE-600)2702232-8$$a10.1039/D2TA00078D$$gVol. 10, no. 18, p. 10069 - 10082$$n18$$p10069 - 10082$$tJournal of materials chemistry / A$$v10$$x2050-7488$$y2022
000480968 8564_ $$uhttps://bib-pubdb1.desy.de/record/480968/files/Paper.pdf$$yOpenAccess
000480968 8564_ $$uhttps://bib-pubdb1.desy.de/record/480968/files/Paper.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000480968 909CO $$ooai:bib-pubdb1.desy.de:480968$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000480968 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1090762$$aExternal Institute$$b1$$kExtern
000480968 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1083991$$aExternal Institute$$b2$$kExtern
000480968 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1032169$$aExternal Institute$$b4$$kExtern
000480968 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1087875$$aExternal Institute$$b5$$kExtern
000480968 9131_ $$0G:(DE-HGF)POF4-6G3$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vPETRA III (DESY)$$x0
000480968 9141_ $$y2022
000480968 915__ $$0LIC:(DE-HGF)CCBY3$$2HGFVOC$$aCreative Commons Attribution CC BY 3.0
000480968 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000480968 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)9910$$2StatID$$aIF >= 10$$bJ MATER CHEM A : 2019$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0400$$2StatID$$aAllianz-Lizenz / DFG$$d2021-01-28$$wger
000480968 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ MATER CHEM A : 2019$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0430$$2StatID$$aNational-Konsortium$$d2021-01-28$$wger
000480968 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2021-01-28
000480968 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2021-01-28
000480968 9201_ $$0I:(DE-H253)PETRA_III-20150811$$kPETRA III$$lPETRA III$$x0
000480968 980__ $$ajournal
000480968 980__ $$aVDB
000480968 980__ $$aUNRESTRICTED
000480968 980__ $$aI:(DE-H253)PETRA_III-20150811
000480968 9801_ $$aFullTexts