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@ARTICLE{Schwarzkopf:480620,
author = {Schwarzkopf, Jutta and Braun, Dorothee and Hanke, Michael
and Uecker, Reinhard and Schmidbauer, Martin},
title = {{S}train {E}ngineering of {F}erroelectric {D}omains in
${K}x{N}a_{1−x}{N}b{O}_3$ {E}pitaxial {L}ayers},
journal = {Frontiers in Materials},
volume = {4},
issn = {2296-8016},
address = {Lausanne},
publisher = {Frontiers Media},
reportid = {PUBDB-2022-03901},
pages = {26},
year = {2017},
abstract = {The application of lattice strain through epitaxial growth
of oxide films on lattice mismatched perovskite-like
substrates strongly influences the structural properties of
ferroelectric domains and their corresponding piezoelectric
behavior. The formation of different ferroelectric phases
can be understood by a strain-phase diagram, which is
calculated within the framework of the
Landau–Ginzburg–Devonshire theory. In this paper, we
illustrate the opportunity of ferroelectric domain
engineering in the KxNa1−xNbO3 lead-free material system.
In particular, the following examples are discussed in
detail: (i) Different substrates (NdGaO3, SrTiO3, DyScO3,
TbScO3, and GdScO3) are used to systematically tune the
incorporated epitaxial strain from compressive to tensile.
This can be exploited to adjust the NaNbO3 thin film surface
orientation and, concomitantly, the vector of electrical
polarization, which rotates from mainly vertical to
exclusive in-plane orientation. (ii) In ferroelectric
NaNbO3, thin films grown on rare-earth scandate substrates,
highly regular stripe domain patterns are observed. By using
different film thicknesses, these can be tailored with
regard to domain periodicity and vertical polarization
component. (iii) A featured potassium concentration of x =
0.9 of KxNa1−xNbO3 thin films grown on (110) NdScO3
substrates favors the coexistence of two equivalent,
monoclinic, but differently oriented ferroelectric phases. A
complicated herringbone domain pattern is experimentally
observed which consists of alternating MC and a1a2 domains.
The coexistence of different types of ferroelectric domains
leads to polarization discontinuities at the domain walls,
potentially enabling high piezoelectric responses. In each
of these examples, the experimental results are in excellent
agreement with predictions based on the linear elasticity
theory.},
cin = {DOOR ; HAS-User},
ddc = {620},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
experiment = {EXP:(DE-H253)D-BW2-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000418962500001},
doi = {10.3389/fmats.2017.00026},
url = {https://bib-pubdb1.desy.de/record/480620},
}