% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Amann:479771,
      author       = {Amann, Peter and Klötzer, Bernhard and Degerman, David and
                      Köpfle, Norbert and Goetsch, Thomas and Lömker, Patrick
                      and Rameshan, Christoph and Ploner, Kevin and Bikaljevic,
                      Djuro and Wang, Hsin-Yi and Soldemo, Markus and Shipilin,
                      Mikhail and Goodwin, Christopher M. and Gladh, Jörgen and
                      Halldin Stenlid, Joakim and Börner, Mia and Schlueter,
                      Christoph and Nilsson, Anders},
      title        = {{T}he state of zinc in methanol synthesis over a
                      {Z}n/{Z}n{O}/{C}u(211) model catalyst},
      journal      = {Science},
      volume       = {376},
      number       = {6593},
      issn         = {0036-8075},
      address      = {Cambridge, Mass.},
      publisher    = {Moses King},
      reportid     = {PUBDB-2022-03204},
      pages        = {603 - 608},
      year         = {2022},
      note         = {Waiting for fulltext},
      abstract     = {The active chemical state of zinc (Zn) in a zinc-copper
                      (Zn-Cu) catalyst during carbon dioxide/carbon monoxide
                      (CO$_2$/CO) hydrogenation has been debated to be Zn oxide
                      (ZnO) nanoparticles, metallic Zn, or a Zn-Cu surface alloy.
                      We used x-ray photoelectron spectroscopy at 180 to 500
                      millibar to probe the nature of Zn and reaction
                      intermediates during CO$_2$/CO hydrogenation over
                      Zn/ZnO/Cu(211), where the temperature is sufficiently high
                      for the reaction to rapidly turn over, thus creating an
                      almost adsorbate-free surface. Tuning of the grazing
                      incidence angle makes it possible to achieve either surface
                      or bulk sensitivity. Hydrogenation of CO$_2$ gives
                      preference to ZnO in the form of clusters or nanoparticles,
                      whereas in pure CO a surface Zn-Cu alloy becomes more
                      prominent. The results reveal a specific role of CO in the
                      formation of the Zn-Cu surface alloy as an active phase that
                      facilitates efficient CO$_2$ methanol synthesis.},
      cin          = {DOOR ; HAS-User / FS-PET-S},
      ddc          = {500},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PET-S-20190712},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: II-20190003 EC (II-20190003-EC) / SWEDEN-DESY -
                      SWEDEN-DESY Collaboration $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)II-20190003-EC /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P22-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:35511988},
      UT           = {WOS:000796932700038},
      doi          = {10.1126/science.abj7747},
      url          = {https://bib-pubdb1.desy.de/record/479771},
}