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@ARTICLE{Degerman:477120,
      author       = {Degerman, David and Shipilin, Mikhail and Lömker, Patrick
                      and Goodwin, Christopher M. and Gericke, Sabrina M. and
                      Hejral, Uta and Gladh, Jörgen and Wang, Hsin-Yi and
                      Schlueter, Christoph and Nilsson, Anders and Amann, Peter},
      title        = {{O}perando {O}bservation of {O}xygenated {I}ntermediates
                      during {CO} {H}ydrogenation on {R}h {S}ingle {C}rystals},
      journal      = {Journal of the American Chemical Society},
      volume       = {144},
      number       = {16},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PUBDB-2022-01916},
      pages        = {7038 - 7042},
      year         = {2022},
      abstract     = {The CO hydrogenation reaction over the Rh(111) and (211)
                      surfaces has been investigated operando by X-ray
                      photoelectron spectroscopy at a pressure of 150 mbar.
                      Observations of the resting state of the catalyst give
                      mechanistic insight into the selectivity of Rh for
                      generating ethanol from CO hydrogenation. This study shows
                      that the Rh(111) surface does not dissociate all CO
                      molecules before hydrogenation of the O and C atoms, which
                      allows methoxy and other both oxygenated and hydrogenated
                      species to be visible in the photoelectron spectra.},
      cin          = {DOOR ; HAS-User / FS-PET-S},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PET-S-20190712},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: I-20191434 EC (I-20191434-EC) / SWEDEN-DESY -
                      SWEDEN-DESY Collaboration $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)I-20191434-EC /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P22-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:35394273},
      UT           = {WOS:000799141600003},
      doi          = {10.1021/jacs.2c00300},
      url          = {https://bib-pubdb1.desy.de/record/477120},
}