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@ARTICLE{Burt:475622,
author = {Burt, Michael and Minion, Louis and Lee, Jason Wai Lung},
title = {{P}redicting {C}oulomb explosion fragment angular
distributions using molecular ground-state vibrational
motion},
journal = {Physical chemistry, chemical physics},
volume = {24},
number = {19},
issn = {1463-9076},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PUBDB-2022-01382},
pages = {11636 - 11645},
year = {2022},
abstract = {Laser-induced Coulomb explosions can be used to identify
gas-phase molecular structures through correlations
betweenfragment ion trajectories. This report presents a
model for predicting these outcomes, which first establishes
the neutralequilibrium geometry of a target molecule using
electronic structure calculations, and then samples a
probability distributionof potential ground-state
configurations by allowing for zero-point vibrational
motion. Candidate structuresare assumed to explode
instantaneously into charged fragments, and the simulated
ion trajectories are correlated usingrecoil-frame covariance
analysis. The effects of detection efficiency and
fluctuating experimental conditions are alsoconsidered. The
results were found to match experimental data, indicating
that Coulomb explosion fragment angulardistributions
produced from highly-charged ions depend largely on the
internal motion of the target molecule.},
cin = {FS-SMP},
ddc = {540},
cid = {I:(DE-H253)FS-SMP-20171124},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631)},
pid = {G:(DE-HGF)POF4-631},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {35521679},
UT = {WOS:000791982000001},
doi = {10.1039/D2CP01114J},
url = {https://bib-pubdb1.desy.de/record/475622},
}