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@ARTICLE{Potorochin:475352,
author = {Potorochin, Dmitrii and Chaika, Alexander N. and
Molodtsova, Olga and Aristov, Victor and Marchenko, Dmitry
E. and Smirnov, Dmitry A. and Makarova, Anna A. and Walls,
Brian and Zhussupbekov, Kuanysh and Walshe, Killian and
Shvets, Igor V. and Ciobanu, Anca Simona and Rabchinskii,
Maxim K. and Ulin, Nikolai V. and Baidakova, Marina V. and
Brunkov, Pavel N. and Molodtsov, Serguei},
title = {{S}urface functionalization of few-layer graphene on β
-{S}i{C}(001) by {N}eutral {R}ed dye},
journal = {Applied surface science},
volume = {585},
issn = {0169-4332},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {PUBDB-2022-01333},
pages = {152542},
year = {2022},
abstract = {Few-layer graphene on -SiC(001) functionalized with
phenazine dye Neutral Red by means of diazonium chemistry
has been studied using X-ray photoelectron spectroscopy,
near-edge X-ray absorption fine structure, photoemission
electron microscopy, scanning tunneling microscopy, and
density functional theory calculations. The experimental
data reveal the formation of a composite phenazine
dye/graphene structure with a large energy gap. The
molecules in this structure can be oriented both parallel
and perpendicular to the graphene surface. According to
scanning tunneling spectroscopy and theoretical
calculations, the density of electron states in different
surface areas depends on the local short-range order and the
molecules’ environment. On the other hand, the
photoemission spectroscopy study shows that the bottom
layers of the few-layer graphene remain intact, which
inherently makes the synthesized layered composite a
low-dimensional metal/semiconductor heterostructure. In
addition, photoemission electron microscopy imaging shows a
high homogeneity of the dye-modified graphene on a
micrometer scale.},
cin = {FS-PETRA-S / FS-TI / DOOR ; HAS-User / $XFEL_E2_THE$},
ddc = {660},
cid = {I:(DE-H253)FS-PETRA-S-20210408 / I:(DE-H253)FS-TI-20120731
/ I:(DE-H253)HAS-User-20120731 /
$I:(DE-H253)XFEL_E2_THE-20210408$},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3)},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3},
experiment = {EXP:(DE-H253)P-P04-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000784440300001},
doi = {10.1016/j.apsusc.2022.152542},
url = {https://bib-pubdb1.desy.de/record/475352},
}