Dissertation / PhD Thesis PUBDB-2022-01216

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Synthesis and study of the correlation between the atomic and electronic structure of low-dimensional carbon-based nanomaterials

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2021

144 pp. () = Dissertation, TU Bergakademie Freiberg, 2021  GO

Abstract: Current work is devoted to synthesizing and studying atomic and electronic structure of several low-dimensional carbon-based nanomaterials, which can be of interest for fabrication of advanced electronic devices. All of them exhibit a $\pi$-conjugated structure, which promises high stability and endurance in the case of employment in technological applications. Chapters 1 and 2 serve for a general introduction and description of experimental techniques used to investigate the low-dimensional carbon-based nano-materials in the current work. The first example is mono-, bi-, and tri-layer graphene grown on cubic-SiC(001). Chapter 3 depicts investigation of the atomic and electronic structure of graphene depending on the number of its layers epitaxially grown on SiC substrate. The feasibility of facile CVD growth of cubic-SiC on conventional silicon wafers makes such graphene type compatible with existing silicon technologies. Hence, it is a good candidate for embedding into existing routines of electronic device fabrication. Chapter 4 is dedicated to investigating composite structure obtained via chemical modification of few-layer graphene on cubic-SiC(001) with Neutral red dye derivatives using the diazonium chemistry approach. This results in the synthesis of a layered structure, the surface layer of which exhibits semiconducting properties while buried graphene layers stay semimetallic. Such a system may be of interest for optoelectronic applications. Chapter 5 focuses on study of hybrid organic-inorganic systems consisting of semiconducting thin films of planar tetrafluoro-substituted copper phthalocyanine molecules (CuPcF$_4$) with self-organized indium nanoparticles of variable size at its surface and in the volume. Such thin films can be considered for application as an active layer in resistive random-access memory devices.


Note: Dissertation, TU Bergakademie Freiberg, 2021

Contributing Institute(s):
  1. PETRA-S (FS-PETRA-S)
  2. SCS (XFEL_E2_SCS)
Research Program(s):
  1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
  2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
  3. PHGS, VH-GS-500 - PIER Helmholtz Graduate School (2015_IFV-VH-GS-500) (2015_IFV-VH-GS-500)
Experiment(s):
  1. PETRA Beamline P04 (PETRA III)
  2. SCS: Spectroscopy & Coherent Scattering (SASE3)

Appears in the scientific report 2021
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The record appears in these collections:
Private Collections > >DESY > >FS > FS-PETRA-S
Private Collections > >XFEL.EU > XFEL_E2_SCS
Document types > Theses > Ph.D. Theses
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 Record created 2022-02-17, last modified 2023-11-08


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