Home > Publications database > Structure of binary antimony phosphate glasses by diffraction methods > print

001     474968
005     20250724151357.0
024 7 _ |a 10.1016/j.jnoncrysol.2022.121476
|2 doi
024 7 _ |a 0022-3093
|2 ISSN
024 7 _ |a 1873-4812
|2 ISSN
024 7 _ |a 10.3204/PUBDB-2022-01094
|2 datacite_doi
024 7 _ |a WOS:000789673600004
|2 WOS
024 7 _ |a openalex:W4213219699
|2 openalex
037 _ _ |a PUBDB-2022-01094
082 _ _ |a 670
100 1 _ |a Hoppe, Uwe
|0 P:(DE-H253)PIP1009924
|b 0
|e Corresponding author
245 _ _ |a Structure of binary antimony phosphate glasses by diffraction methods
260 _ _ |a Amsterdam [u.a.]
|c 2022
|b Elsevier Science
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1678279488_6416
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a Antimony phosphate glasses (Sb$_2$O$_3$)x(P$_2$O$_5$)$_{1-x}$ with $x$ = 0.05 and 0.80 were measured by neutron and X-ray diffraction with high real-space resolution. The P−O and O−O distance peaks of the PO$_4$ tetrahedra were found with the expected parameters. For the glass of $x$ = 0.80 the Sb−O and O−O coordination numbers and distances suggest highly distorted SbO$_3$ and SbO$_4$ environments according to strong lone-pair effects of the Sb$^{3+}$. The fraction of SbO$_4$ has the right portion that all oxygens can form Sb−O−Sb or Sb−O−P bridges. Significant numbers of secondary Sb−O bonds (> 0.25 nm) are extracted. The first diffraction peak at 13 nm$^{−1}$ is related to distances between stacked layers of corner-connected oxygen triangles as in the orthorhombic Sb$_2$O$_3$. For the glass of $x$ = 0.05 the medium-range order reminds that of vitreous P$_2$O$_5$. Its SbO$_4$ units are formed with mean Sb−O bonds of 0.210 nm.
536 _ _ |a 631 - Matter – Dynamics, Mechanisms and Control (POF4-631)
|0 G:(DE-HGF)POF4-631
|c POF4-631
|f POF IV
|x 0
588 _ _ |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de
693 _ _ |a DORIS III
|f DORIS Beamline BW5
|1 EXP:(DE-H253)DORISIII-20150101
|0 EXP:(DE-H253)D-BW5-20150101
|6 EXP:(DE-H253)D-BW5-20150101
|x 0
700 1 _ |a Schöps, A.
|0 P:(DE-H253)PIP1000495
|b 1
|u desy
700 1 _ |a Hannon, Alex
|0 P:(DE-H253)PIP1012057
|b 2
700 1 _ |a Barz, A.
|0 P:(DE-HGF)0
|b 3
700 1 _ |a Stachel, D.
|0 P:(DE-HGF)0
|b 4
773 _ _ |a 10.1016/j.jnoncrysol.2022.121476
|g Vol. 583, p. 121476 -
|0 PERI:(DE-600)1500501-X
|p 121476 -
|t Journal of non-crystalline solids
|v 583
|y 2022
|x 0022-3093
856 4 _ |y Restricted
|u https://bib-pubdb1.desy.de/record/474968/files/JoNonCrystSol_583_121476_2022.pdf
856 4 _ |y Restricted
|x pdfa
|u https://bib-pubdb1.desy.de/record/474968/files/JoNonCrystSol_583_121476_2022.pdf?subformat=pdfa
856 4 _ |y Published on 2022-05-01. Available in OpenAccess from 2023-05-01.
|z StatID:(DE-HGF)0510
|u https://bib-pubdb1.desy.de/record/474968/files/NOC-D-22-00018.pdf
856 4 _ |y Restricted
|z StatID:(DE-HGF)0599
|u https://bib-pubdb1.desy.de/record/474968/files/csbp22.pdf
856 4 _ |y Published on 2022-05-01. Available in OpenAccess from 2023-05-01.
|x pdfa
|z StatID:(DE-HGF)0510
|u https://bib-pubdb1.desy.de/record/474968/files/NOC-D-22-00018.pdf?subformat=pdfa
856 4 _ |y Restricted
|x pdfa
|z StatID:(DE-HGF)0599
|u https://bib-pubdb1.desy.de/record/474968/files/csbp22.pdf?subformat=pdfa
909 C O |o oai:bib-pubdb1.desy.de:474968
|p openaire
|p open_access
|p VDB
|p driver
|p dnbdelivery
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 0
|6 P:(DE-H253)PIP1009924
910 1 _ |a Deutsches Elektronen-Synchrotron
|0 I:(DE-588b)2008985-5
|k DESY
|b 1
|6 P:(DE-H253)PIP1000495
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 2
|6 P:(DE-H253)PIP1012057
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF4-630
|0 G:(DE-HGF)POF4-631
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-600
|4 G:(DE-HGF)POF
|v Matter – Dynamics, Mechanisms and Control
|x 0
914 1 _ |y 2022
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
|d 2021-01-27
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0160
|2 StatID
|b Essential Science Indicators
|d 2021-01-27
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0600
|2 StatID
|b Ebsco Academic Search
|d 2021-01-27
915 _ _ |a Embargoed OpenAccess
|0 StatID:(DE-HGF)0530
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
|d 2021-01-27
915 _ _ |a WoS
|0 StatID:(DE-HGF)0113
|2 StatID
|b Science Citation Index Expanded
|d 2021-01-27
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
|d 2021-01-27
915 _ _ |a Peer Review
|0 StatID:(DE-HGF)0030
|2 StatID
|b ASC
|d 2021-01-27
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J NON-CRYST SOLIDS : 2019
|d 2021-01-27
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
|d 2021-01-27
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
|d 2021-01-27
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
|d 2021-01-27
920 1 _ |0 I:(DE-H253)FS-DO-20120731
|k FS-DO
|l FS-Experimentebetreuung DORIS
|x 0
920 1 _ |0 I:(DE-H253)FS-US-20120731
|k FS-US
|l FS-Undulator Systeme
|x 1
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-H253)FS-DO-20120731
980 _ _ |a I:(DE-H253)FS-US-20120731
980 1 _ |a FullTexts

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21