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000474968 0247_ $$2ISSN$$a1873-4812
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000474968 1001_ $$0P:(DE-H253)PIP1009924$$aHoppe, Uwe$$b0$$eCorresponding author
000474968 245__ $$aStructure of binary antimony phosphate glasses by diffraction methods
000474968 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2022
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000474968 520__ $$aAntimony phosphate glasses (Sb$_2$O$_3$)x(P$_2$O$_5$)$_{1-x}$ with $x$ = 0.05 and 0.80 were measured by neutron and X-ray diffraction with high real-space resolution. The P−O and O−O distance peaks of the PO$_4$ tetrahedra were found with the expected parameters. For the glass of $x$ = 0.80 the Sb−O and O−O coordination numbers and distances suggest highly distorted SbO$_3$ and SbO$_4$ environments according to strong lone-pair effects of the Sb$^{3+}$. The fraction of SbO$_4$ has the right portion that all oxygens can form Sb−O−Sb or Sb−O−P bridges. Significant numbers of secondary Sb−O bonds (> 0.25 nm) are extracted. The first diffraction peak at 13 nm$^{−1}$ is related to distances between stacked layers of corner-connected oxygen triangles as in the orthorhombic Sb$_2$O$_3$. For the glass of $x$ = 0.05 the medium-range order reminds that of vitreous P$_2$O$_5$. Its SbO$_4$ units are formed with mean Sb−O bonds of 0.210 nm. 
000474968 536__ $$0G:(DE-HGF)POF4-631$$a631 - Matter – Dynamics, Mechanisms and Control (POF4-631)$$cPOF4-631$$fPOF IV$$x0
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000474968 7001_ $$0P:(DE-H253)PIP1000495$$aSchöps, A.$$b1$$udesy
000474968 7001_ $$0P:(DE-H253)PIP1012057$$aHannon, Alex$$b2
000474968 7001_ $$0P:(DE-HGF)0$$aBarz, A.$$b3
000474968 7001_ $$0P:(DE-HGF)0$$aStachel, D.$$b4
000474968 773__ $$0PERI:(DE-600)1500501-X$$a10.1016/j.jnoncrysol.2022.121476$$gVol. 583, p. 121476 -$$p121476 -$$tJournal of non-crystalline solids$$v583$$x0022-3093$$y2022
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