Home > Publications database > Effect of the microstructure of graphitic boron nitride on the kinetics of the formation of boron nitride high-pressure phases > print |
001 | 474900 | ||
005 | 20250729163432.0 | ||
024 | 7 | _ | |a 10.1016/j.jeurceramsoc.2018.10.021 |2 doi |
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041 | _ | _ | |a English |
082 | _ | _ | |a 660 |
100 | 1 | _ | |a Schimpf, Christian |0 P:(DE-H253)PIP1008849 |b 0 |e Corresponding author |
245 | _ | _ | |a Effect of the microstructure of graphitic boron nitride on the kinetics of the formation of boron nitride high-pressure phases |
260 | _ | _ | |a Amsterdam [u.a.] |c 2019 |b Elsevier Science |
336 | 7 | _ | |a article |2 DRIVER |
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336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1645449233_1084 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
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336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
520 | _ | _ | |a Three types of hexagonal boron nitride (h-BN) with graphitic crystal structure having different microstructures were subjected to high pressures (HP) and high temperatures (HT), and the kinetics of the phase transitions to the sp$^3$-hybridized phases (w-BN, c-BN) was studied using in situ synchrotron diffraction. The analysis of the phase transformation kinetics revealed the transformation paths and activation energies E$_a$ of the transformation of h-BN to the high-pressure forms of BN for different microstructures of h-BN. Defect-poor h-BN transforms to metastable wurtzitic BN (w-BN) with E$_a$ ≈ 0.3 eV/at. Defect-rich forms of h-BN transform directly to c-BN, but with a higher activation energy. It was observed that the turbostratic disorder in h-BN retards the phase transition as compared to h-BN containing corrugated basal planes and a low degree of turbostracity. The experimental results are discussed in view of the microstructure changes during the HP/HT treatment and compared to available theoretical phase transition models. |
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700 | 1 | _ | |a Schwarz, Marcus |0 P:(DE-H253)PIP1008544 |b 1 |
700 | 1 | _ | |a Lathe, C. |0 P:(DE-H253)PIP1002121 |b 2 |
700 | 1 | _ | |a Kroke, E. |0 P:(DE-HGF)0 |b 3 |
700 | 1 | _ | |a Rafaja, D. |0 P:(DE-H253)PIP1026941 |b 4 |
773 | _ | _ | |a 10.1016/j.jeurceramsoc.2018.10.021 |g Vol. 39, no. 4, p. 944 - 951 |0 PERI:(DE-600)2013983-4 |n 4 |p 944 - 951 |t Journal of the European Ceramic Society |v 39 |y 2019 |x 0955-2219 |
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