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@ARTICLE{Klacsov:474186,
      author       = {Klacsová, Mária and Bóta, Attila and Westh, Peter and
                      Funari, Sergio de Souza and Uhríková, Daniela and
                      Balgavý, Pavol},
      title        = {{T}hermodynamic and structural study of {DMPC}–alkanol
                      systems},
      journal      = {Physical chemistry, chemical physics},
      volume       = {23},
      number       = {14},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PUBDB-2022-00576},
      pages        = {8598 - 8606},
      year         = {2021},
      note         = {Waiting for fulltext},
      abstract     = {The thermodynamic and structural behaviors of lamellar
                      dimyristoylphosphatidylcholine-alkanol (abbreviation
                      DMPC–CnOH, n = 8–18 is the even number of carbons in the
                      alkyl chain) systems were studied by using DSC and SAXD/WAXD
                      methods at a 0–0.8 CnOH : DMPC molar ratio range. Up
                      to n ≤ 10 a significant biphasic effect depending on the
                      main transition temperature t$_m$ on the CnOH concentration
                      was observed. Two breakpoints were revealed: turning point
                      (TP), corresponding to the minimum, and threshold
                      concentration (c$_T$), corresponding to the end of the
                      biphasic tendency. These breakpoints were also observed in
                      the alkanol concentration dependent change in the enthalpy
                      of the main transition ΔH$_m$. In the case of CnOHs with n
                      > 10 we propose a marked shift of TP and c$_T$ to very low
                      concentrations; consequently, only increase of tm is
                      observed. A partial phase diagram was constructed for a
                      pseudo-binary DMPC–C12OH system. We suggest a
                      fluid–fluid immiscibility of the DMPC–C12OH system above
                      c$_T$ with a consequent formation of domains with different
                      C12OH contents. At a constant CnOH concentration, the
                      effects of CnOHs on ΔH$_m$ and bilayer repeat distance were
                      found to depend predominantly on the mismatch between CnOH
                      and lipid chain lengths. Observed effects are suggested to
                      be underlined by a counterbalancing effect of interchain van
                      der Waals interactions and headgroup repulsion.},
      cin          = {DOOR ; HAS-User / FS-PETRA-D},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PETRA-D-20210408},
      pnm          = {633 - Life Sciences – Building Blocks of Life: Structure
                      and Function (POF4-633)},
      pid          = {G:(DE-HGF)POF4-633},
      experiment   = {EXP:(DE-H253)D-A2-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {33876021},
      UT           = {WOS:000633043800001},
      doi          = {10.1039/D0CP04991C},
      url          = {https://bib-pubdb1.desy.de/record/474186},
}