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000473652 1001_ $$0P:(DE-H253)PIP1097792$$aWarne, Emily M.$$b0
000473652 245__ $$aTime resolved detection of the S($^1$D) product of the UV induced dissociation of CS$_2$
000473652 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2021
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000473652 520__ $$aThe products formed following the photodissociation of UV (200 nm) excited CS$_2$ are monitored in a time resolved photoelectron spectroscopy experiment using femtosecond XUV (21.5 eV) photons. By spectrally resolving the electrons, we identify separate photoelectron bands related to the CS$_2$ + hν → S($^1$D) + CS and CS$_2$ + hν → S($^3$P) + CS dissociation channels, which show different appearance and rise times. The measurements show that there is no delay in the appearance of the S(1D) product contrary to the results of Horio et al. [J. Chem. Phys. 147, 013932 (2017)]. Analysis of the photoelectron yield associated with the atomic products allows us to obtain a S($^3$P)/S($^1$D) branching ratio and the rate constants associated with dissociation and intersystem crossing rather than the effective lifetime observed through the measurement of excited state populations alone.
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000473652 7001_ $$0P:(DE-HGF)0$$aSmith, Adam D.$$b1
000473652 7001_ $$0P:(DE-H253)PIP1018933$$aHorke, Daniel A.$$b2
000473652 7001_ $$00000-0002-9121-3698$$aSpringate, Emma$$b3
000473652 7001_ $$00000-0002-7930-0967$$aJones, Alfred J. H.$$b4
000473652 7001_ $$0P:(DE-HGF)0$$aCacho, Cephise$$b5
000473652 7001_ $$00000-0002-4622-8305$$aChapman, Richard T.$$b6
000473652 7001_ $$0P:(DE-H253)PIP1095464$$aMinns, Russell$$b7$$eCorresponding author
000473652 773__ $$0PERI:(DE-600)1473050-9$$a10.1063/5.0035045$$gVol. 154, no. 3, p. 034302 -$$n3$$p034302 $$tThe journal of chemical physics$$v154$$x0021-9606$$y2021
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