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@ARTICLE{Robinson:473651,
      author       = {Robinson, Matthew S. and Niebuhr, Mario and Lever, Fabiano
                      and Mayer, Dennis and Metje, Jan and Gühr, Markus},
      title        = {{U}ltrafast {P}hoto-ion {P}robing of the {R}ing-{O}pening
                      {P}rocess in {T}rans-{S}tilbene {O}xide},
      journal      = {Chemistry - a European journal},
      volume       = {27},
      number       = {44},
      issn         = {0947-6539},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2022-00164},
      pages        = {11418 - 11427},
      year         = {2021},
      abstract     = {The ultrafast photo-induced ring opening of the oxirane
                      derivative trans-stilbene oxide has been studied through the
                      use of ultrafast UV/UV pump-probe spectroscopy by using
                      photo-ion detection. Single- and multiphoton probe paths and
                      final states were identified through comparisons between UV
                      power studies and synchrotron-based vacuum ultraviolet (VUV)
                      single-photon ionization studies. Three major time-dependent
                      features of the parent ion (sub-450 fs decay,
                      (1.5±0.2) ps, and >100 ps) were observed. These decays
                      are discussed in conjunction with the primary ring-opening
                      mechanism of stilbene oxide, which occurs through C−C
                      dissociation in the oxirane ring. The appearance of
                      fragments relating to the masses of dehydrogenated
                      diphenylmethane (167 amu) and dehydrogenated methylbenzene
                      (90 amu) were also investigated. The appearance of the
                      167 amu fragment could suggest an alternative ultrafast
                      ring-opening pathway via the dissociation of one of the
                      C−O bonds within the oxirane ring.},
      cin          = {FS-CFEL-CMI},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-CFEL-CMI-20220405},
      pnm          = {633 - Life Sciences – Building Blocks of Life: Structure
                      and Function (POF4-633)},
      pid          = {G:(DE-HGF)POF4-633},
      experiment   = {EXP:(DE-MLZ)External-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34037274},
      UT           = {WOS:000662737000001},
      doi          = {10.1002/chem.202101343},
      url          = {https://bib-pubdb1.desy.de/record/473651},
}