% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Loru:472643,
author = {Loru, Donatella and Steber, Amanda and Schnell, Melanie and
Rijs, Anouk and Rap, Daniel Benjamin and Lemmens, Alexander
and Thunnissen, Johannes M. M.},
title = {{N}ew potential candidates for astronomical searches
discovered in the electrical discharge of the {PAH}
naphthalene and acetonitrile},
journal = {Journal of molecular spectroscopy},
volume = {386},
issn = {0022-2852},
address = {Orlando, Fla.},
publisher = {Academic Press},
reportid = {PUBDB-2021-05142},
pages = {111629},
year = {2022},
abstract = {The formation and dissociation mechanisms of polycyclic
aromatic hydrocarbons (PAHs) as well as their reactivity
with other interstellar molecules are elusive. In this work,
we have investigated the electrical discharge chemistry of
the PAH naphthalene and acetonitrile, a molecule known to be
present in interstellar environments, using a combination of
mass-selective IR-UV ion dip spectroscopy with the free
electron laser FELIX in the mid-IR frequency region (550 –
1800 cm$^{-1}$), and quantum chemical calculations. In
addition to the species known to be produced in the
electrical discharge of pure naphthalene, –CH$_3$ and
–CN substituted unsaturated hydrocarbons have been
identified. Most of them, in particular those containing a
nitrogen atom in the molecular framework, such as
benzo[7]annulene‐6‐carbonitrile, have a substantial
dipole moment and, therefore, can be considered as potential
candidates for astronomical searches. Among the species
observed, the two isomers 1- and 2-cyanonaphthalene, which
have been recently detected in the TMC-1, have been
unambiguously identified in our experiment, thus
highlighting the use of electrical discharge sources as a
valuable tool to produce astronomically relevant species.},
cin = {FS-SMP},
ddc = {530},
cid = {I:(DE-H253)FS-SMP-20171124},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / ASTROROT - Unraveling interstellar chemistry
with broadband microwave spectroscopy and next-generation
telescope arrays (638027)},
pid = {G:(DE-HGF)POF4-631 / G:(EU-Grant)638027},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000797332600003},
doi = {10.1016/j.jms.2022.111629},
url = {https://bib-pubdb1.desy.de/record/472643},
}