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@ARTICLE{Pallach:465319,
      author       = {Pallach, Roman and Keupp, Julian and Terlinden, Kai and
                      Frentzel-Beyme, Louis and Kloss, Marvin and Machalica,
                      Andrea and Kotschy, Julia and Vasa, Suresh K. and Chater,
                      Philip A. and Sternemann, Christian and Wharmby, Michael T.
                      and Linser, Rasmus and Schmid, Rochus and Henke, Sebastian},
      title        = {{F}rustrated flexibility in metal-organic frameworks},
      journal      = {Nature Communications},
      volume       = {12},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Nature Publishing Group UK},
      reportid     = {PUBDB-2021-03843},
      pages        = {4097},
      year         = {2021},
      abstract     = {Stimuli-responsive flexible metal-organic frameworks (MOFs)
                      remain at the forefront of porous materials research due to
                      their enormous potential for various technological
                      applications. Here, we introduce the concept of frustrated
                      flexibility in MOFs, which arises from an incompatibility of
                      intra-framework dispersion forces with the geometrical
                      constraints of the inorganic building units. Controlled by
                      appropriate linker functionalization with dispersion energy
                      donating alkoxy groups, this approach results in a series of
                      MOFs exhibiting a new type of guest- and
                      temperature-responsive structural flexibility characterized
                      by reversible loss and recovery of crystalline order under
                      full retention of framework connectivity and topology. The
                      stimuli-dependent phase change of the frustrated MOFs
                      involves non-correlated deformations of their inorganic
                      building unit, as probed by a combination of global and
                      local structure techniques together with computer
                      simulations. Frustrated flexibility may be a common
                      phenomenon in MOF structures, which are commonly regarded as
                      rigid, and thus may be of crucial importance for the
                      performance of these materials in various applications.},
      cin          = {DOOR ; HAS-User / FS-PETRA-D},
      ddc          = {500},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PETRA-D-20210408},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      DFG project 390677874 - EXC 2033: RESOLV (Ruhr Explores
                      Solvation) (390677874)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(GEPRIS)390677874},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34215743},
      UT           = {WOS:000672164300010},
      doi          = {10.1038/s41467-021-24188-4},
      url          = {https://bib-pubdb1.desy.de/record/465319},
}