% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Nalin:465192, author = {Nalin, Giammarco and Fehre, Kilian and Trinter, Florian and Novikovskiy, Nikolay M. and Anders, Nils and Trabert, Daniel and Grundmann, Sven and Kircher, Max and Khan, Arnab and Tomar, Raghu and Hofmann, Max and Waitz, Markus and Vela-Pérez, Isabel and Kastirke, Gregor and Siebert, Juliane and Tsitsonis, Dimitrios and Fukuzawa, Hironobu and Ueda, Kiyoshi and Williams, Joshua and Kargin, Denis and Maurer, Martin and Kuestner-Wetekam, Catmarna and Marder, Lutz and Viehmann, Johannes and Knie, Andre and Jahnke, Till and Ilchen, Markus and Doerner, Reinhard and Pietschnig, Rudolf and Demekhin, Philipp and Schoeffler, Markus}, title = {{P}hotoelectron circular dichroism of {O} 1s-photoelectrons of uniaxially oriented trifluoromethyloxirane: energy dependence and sensitivity to molecular configuration}, journal = {Physical chemistry, chemical physics}, volume = {23}, number = {32}, issn = {1463-9084}, address = {Cambridge}, publisher = {RSC Publ.}, reportid = {PUBDB-2021-03802, arXiv:2106.08071}, pages = {17248 - 17258}, year = {2021}, abstract = {The photoelectron circular dichroism (PECD) of the O 1s-photoelectrons of trifluoromethyloxirane (TFMOx) is studied experimentally and theoretically for different photoelectron kinetic energies. The experiments were performed employing circularly polarized synchrotron radiation and coincident electron and fragment ion detection using cold target recoil ion momentum spectroscopy. The corresponding calculations were performed by means of the single center method within the relaxed-core Hartree–Fock approximation. We concentrate on the energy dependence of the differential PECD of uniaxially oriented TFMOx molecules, which is accessible through the employed coincident detection. We also compare the results for the differential PECD of TFMOx to those obtained for the equivalent fragmentation channel and similar photoelectron kinetic energy of methyloxirane (MOx), studied in our previous work. Thereby, we investigate the influence of the substitution of the methyl group by the trifluoromethyl group at the chiral center on the molecular chiral response. Finally, the presently obtained angular distribution parameters are compared to those available in the literature.}, cin = {FS-PETRA-S / UFrankf. / DOOR ; HAS-User}, ddc = {540}, cid = {I:(DE-H253)FS-PETRA-S-20210408 / $I:(DE-H253)UFrankf_-20120814$ / I:(DE-H253)HAS-User-20120731}, pnm = {631 - Matter – Dynamics, Mechanisms and Control (POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3)}, pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3}, experiment = {EXP:(DE-H253)P-P04-20150101}, typ = {PUB:(DE-HGF)16}, pubmed = {pmid:34346440}, eprint = {2106.08071}, howpublished = {arXiv:2106.08071}, archivePrefix = {arXiv}, SLACcitation = {$\%\%CITATION$ = $arXiv:2106.08071;\%\%$}, UT = {WOS:000680882400001}, doi = {10.1039/D1CP02462K}, url = {https://bib-pubdb1.desy.de/record/465192}, }