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@ARTICLE{Jurgeleit:462678,
      author       = {Jurgeleit, Ramona and Grimm-Lebsanft, Benjamin and Flöser,
                      Benedikt Maria and Teubner, Melissa and Buchenau, Soeren and
                      Senft, Laura and Hoffmann, Jonas and Naumova, Maria and
                      Näther, Christian and Ivanović-Burmazović, Ivana and
                      Rübhausen, Michael and Tuczek, Felix},
      title        = {{C}atalytic {O}xygenation of {H}ydrocarbons by
                      {M}ono‐μ‐oxo {D}icopper({II}) {S}pecies {R}esulting
                      from {O}−{O} {C}leavage of {T}etranuclear {C}u {I} /{C}u
                      {II} {P}eroxo {C}omplexes},
      journal      = {Angewandte Chemie / International edition},
      volume       = {60},
      number       = {25},
      issn         = {1521-3773},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2021-03519},
      pages        = {14154-14162},
      year         = {2021},
      abstract     = {One of the challenges of catalysis is the transformation of
                      inert C−H bonds to useful products. Copper-containing
                      monooxygenases play an important role in this regard. Here
                      we show that low-temperature oxygenation of dinuclear
                      copper(I) complexes leads to unusual tetranuclear,
                      mixed-valent $μ_4$-peroxo [Cu$^I$/Cu$^{II}$]$_2$ complexes.
                      These Cu$_4$O$_2$ intermediates promote irreversible and
                      thermally activated O−O bond homolysis, generating Cu$_2$O
                      complexes that catalyze strongly exergonic H-atom
                      abstraction from hydrocarbons, coupled to O-transfer. The
                      Cu$_2$O species can also be produced with N$_2$O,
                      demonstrating their capability for small-molecule
                      activation. The binding and cleavage of O$_2$ leading to the
                      primary Cu$_4$O$_2$ intermediate and the Cu$_2$O complexes,
                      respectively, is elucidated with a range of solution
                      spectroscopic methods and mass spectrometry. The unique
                      reactivities of these species establish an unprecedented,
                      100 \% atom-economic scenario for the catalytic,
                      copper-mediated monooxygenation of organic substrates,
                      employing both O-atoms of O$_2$.},
      cin          = {DOOR ; HAS-User / UNI/INF / UKiel},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      $I:(DE-H253)UNI_INF-20151211$ / I:(DE-H253)UKiel-20120814},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P65-20150101 / EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:33856088},
      UT           = {WOS:000648053600001},
      doi          = {10.1002/anie.202101035},
      url          = {https://bib-pubdb1.desy.de/record/462678},
}