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@ARTICLE{Allum:462475,
      author       = {Allum, Felix and Music, Valerija and Inhester, Ludger and
                      Boll, Rebecca and Erk, Benjamin and Schmidt, Philipp and
                      Baumann, Thomas M. and Brenner, Günter and Burt, Michael
                      and Demekhin, Philipp V. and Dörner, Simon and Ehresmann,
                      Arno and Galler, Andreas and Grychtol, Patrik and Heathcote,
                      David and Kargin, Denis and Larsson, Mats and Lee, Jason W.
                      L. and Li, Zheng and Manschwetus, Bastian and Marder, Lutz
                      and Mason, Robert and Meyer, Michael and Otto, Huda and
                      Passow, Christopher and Pietschnig, Rudolf and Ramm, Daniel
                      and Schubert, Kaja and Schwob, Lucas and Thomas, Richard D.
                      and Vallance, Claire and Vidanović, Igor and von Korff
                      Schmising, Clemens and Wagner, René and Walter, Peter and
                      Zhaunerchyk, Vitali and Rolles, Daniel and Bari, Sadia and
                      Brouard, Mark and Ilchen, Markus},
      title        = {{A} localized view on molecular dissociation via
                      electron-ion partial covariance},
      journal      = {Communications chemistry},
      volume       = {5},
      number       = {1},
      issn         = {2399-3669},
      address      = {[London]},
      publisher    = {Macmillan Publishers Limited, part of Springer Nature},
      reportid     = {PUBDB-2021-03434},
      pages        = {42},
      year         = {2022},
      abstract     = {Inner-shell photoelectron spectroscopy provides an
                      element-specific probe of molecular structure, as
                      core-electron binding energies are sensitive to the chemical
                      environment. Short-wavelength femtosecond light sources,
                      such as Free-Electron Lasers (FELs), even enable
                      time-resolved site-specific investigations of molecular
                      photochemistry. Here, we study the ultraviolet
                      photodissociation of chiral (R/S)-1-iodo-2-methylbutane,
                      probed by XUV pulses from the Free-electron LASer in Hamburg
                      (FLASH) through the ultrafast evolution of the iodine 4d
                      binding energy. Methodologically, we introduce electron-ion
                      partial covariance imaging as a technique to isolate
                      otherwise elusive features in a two-dimensional
                      photoelectron spectrum arising from different
                      photofragmentation pathways. The experimental and
                      theoretical results for the time-resolved electron spectra
                      of the 4d$_{3/2}$ and 4d$_{5/2}$ atomic and molecular levels
                      that are disentangled by this method provide a key step
                      towards studying structural and chemical changes from a
                      specific spectator site. We thus pave the way for
                      approaching femto-stereochemistry with FELs.},
      cin          = {FS-FLASH-D / CFEL-DESYT / FS-FLASH-O / FS-FL / DOOR ;
                      HAS-User / FS-BIG / FS-CFEL-3 / FS-LA},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-FLASH-D-20160930 /
                      I:(DE-H253)CFEL-DESYT-20160930 /
                      I:(DE-H253)FS-FLASH-O-20160930 / I:(DE-H253)FS-FL-20120731 /
                      I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-BIG-20220318 /
                      I:(DE-H253)FS-CFEL-3-20120731 / I:(DE-H253)FS-LA-20130416},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / 6G2 - FLASH (DESY) (POF4-6G2) / FS-Proposal:
                      F-20171078 (F-20171078) / DFG project 328961117 - SFB 1319:
                      Extremes Licht zur Analyse und Kontrolle molekularer
                      Chiralität (ELCH) (328961117) / SFB 755 B03 - Untersuchung
                      ultraschneller Dynamik chemischer Reaktionen mit
                      Femtosekunden-Röntgenpulsen (B03) (50499717) / VH-NG-1104 -
                      Structure and dynamics of gas-phase biomolecules studied by
                      photon-induced ionization and dissociation
                      $(2007_IVF-VH-NG-1104)$},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G2 /
                      G:(DE-H253)F-20171078 / G:(GEPRIS)328961117 /
                      G:(GEPRIS)50499717 / $G:(DE-HGF)2007_IVF-VH-NG-1104$},
      experiment   = {EXP:(DE-H253)F-BL1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000773922700001},
      doi          = {10.1038/s42004-022-00656-w},
      url          = {https://bib-pubdb1.desy.de/record/462475},
}