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000462475 1001_ $$0P:(DE-H253)PIP1032123$$aAllum, Felix$$b0$$eCorresponding author
000462475 245__ $$aA localized view on molecular dissociation via electron-ion partial covariance
000462475 260__ $$a[London]$$bMacmillan Publishers Limited, part of Springer Nature$$c2022
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000462475 520__ $$aInner-shell photoelectron spectroscopy provides an element-specific probe of molecular structure, as core-electron binding energies are sensitive to the chemical environment. Short-wavelength femtosecond light sources, such as Free-Electron Lasers (FELs), even enable time-resolved site-specific investigations of molecular photochemistry. Here, we study the ultraviolet photodissociation of chiral (R/S)-1-iodo-2-methylbutane, probed by XUV pulses from the Free-electron LASer in Hamburg (FLASH) through the ultrafast evolution of the iodine 4d binding energy. Methodologically, we introduce electron-ion partial covariance imaging as a technique to isolate otherwise elusive features in a two-dimensional photoelectron spectrum arising from different photofragmentation pathways. The experimental and theoretical results for the time-resolved electron spectra of the 4d$_{3/2}$ and 4d$_{5/2}$ atomic and molecular levels that are disentangled by this method provide a key step towards studying structural and chemical changes from a specific spectator site. We thus pave the way for approaching femto-stereochemistry with FELs.
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000462475 7001_ $$aMusic, Valerija$$b1
000462475 7001_ $$0P:(DE-H253)PIP1023594$$aInhester, Ludger$$b2$$eCorresponding author
000462475 7001_ $$0P:(DE-H253)PIP1014282$$aBoll, Rebecca$$b3
000462475 7001_ $$0P:(DE-H253)PIP1011809$$aErk, Benjamin$$b4
000462475 7001_ $$aSchmidt, Philipp$$b5
000462475 7001_ $$0P:(DE-H253)PIP1009360$$aBaumann, Thomas M.$$b6
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000462475 7001_ $$aBurt, Michael$$b8
000462475 7001_ $$aDemekhin, Philipp V.$$b9
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000462475 7001_ $$aEhresmann, Arno$$b11
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000462475 7001_ $$aHeathcote, David$$b14
000462475 7001_ $$aKargin, Denis$$b15
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000462475 7001_ $$aLee, Jason W. L.$$b17
000462475 7001_ $$aLi, Zheng$$b18
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000462475 7001_ $$aMarder, Lutz$$b20
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000462475 7001_ $$aMeyer, Michael$$b22
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000462475 7001_ $$0P:(DE-H253)PIP1013418$$aPassow, Christopher$$b24$$udesy
000462475 7001_ $$00000-0003-0551-3633$$aPietschnig, Rudolf$$b25
000462475 7001_ $$0P:(DE-H253)PIP1019336$$aRamm, Daniel$$b26$$udesy
000462475 7001_ $$0P:(DE-H253)PIP1021880$$aSchubert, Kaja$$b27$$udesy
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000462475 7001_ $$aThomas, Richard D.$$b29
000462475 7001_ $$aVallance, Claire$$b30
000462475 7001_ $$0P:(DE-H253)PIP1086150$$aVidanović, Igor$$b31
000462475 7001_ $$0P:(DE-H253)PIP1017973$$avon Korff Schmising, Clemens$$b32
000462475 7001_ $$0P:(DE-H253)PIP1082921$$aWagner, René$$b33
000462475 7001_ $$aWalter, Peter$$b34
000462475 7001_ $$0P:(DE-H253)PIP1018022$$aZhaunerchyk, Vitali$$b35
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000462475 7001_ $$aBrouard, Mark$$b38
000462475 7001_ $$0P:(DE-H253)PIP1007017$$aIlchen, Markus$$b39$$eCorresponding author$$udesy
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