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@ARTICLE{Anker:461902,
      author       = {Anker, Andy S. and Christiansen, Troels Lindahl and Weber,
                      Marcus and Schmiele, Martin and Brok, Erik and Kjær, Emil
                      T. S. and Juhás, Pavol and Thomas, Rico and Mehring,
                      Michael and Jensen, Kirsten Marie},
      title        = {{S}tructural {C}hanges during the {G}rowth of {A}tomically
                      {P}recise {M}etal {O}xido {N}anoclusters from {C}ombined
                      {P}air {D}istribution {F}unction and {S}mall‐{A}ngle
                      {X}‐ray {S}cattering {A}nalysis},
      journal      = {Angewandte Chemie / International edition},
      volume       = {60},
      number       = {37},
      issn         = {1521-3773},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2021-03159},
      pages        = {20407 - 20416},
      year         = {2021},
      abstract     = {The combination of in situ pair distribution function (PDF)
                      analysis and small-angle X-ray scattering (SAXS) enables
                      analysis of the formation mechanism of metal oxido
                      nanoclusters and cluster–solvent interactions as they take
                      place. Herein, we demonstrate the method for the formation
                      of clusters with a [Bi38O45] core. Upon dissolution of
                      crystalline [Bi$_6$O$_5$(OH)$_3$(NO$_3$)$_5$]⋅3 H$_2$O
                      in DMSO, an intermediate rapidly forms, which slowly grows
                      to stable [Bi$_{38}$O$_{45}$] clusters. To identify the
                      intermediate, we developed an automated modeling method,
                      where smaller [BixOy] structures based on the
                      [Bi$_{38}$O$_{45}$] framework are tested against the data.
                      [Bi$_{22}$O$_{26}$] was identified as the main intermediate
                      species, illustrating how combined PDF and SAXS analysis is
                      a powerful tool to gain insight into nucleation on an atomic
                      scale. PDF also provides information on the interaction
                      between nanoclusters and solvent, which is shown to depend
                      on the nature of the ligands on the cluster surface.},
      cin          = {PhotonScience},
      ddc          = {540},
      cid          = {I:(DE-H253)PhotonScience-20170411},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101 /
                      EXP:(DE-H253)P-P07-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34056798},
      UT           = {WOS:000668524300001},
      doi          = {10.1002/anie.202103641},
      url          = {https://bib-pubdb1.desy.de/record/461902},
}