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000461751 1001_ $$0P:(DE-H253)PIP1085949$$aRego, Tomas$$b0
000461751 245__ $$aUnexpected Order–Disorder Transition in Diacetylene Alcohol Langmuir Films
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000461751 520__ $$aThe phase diagram of Langmuir film of diacetylene alcohol – henicosa-5,7-diyn-1-ol – is investigated by means of surface pressure versus surface area isotherms, Brewster Angle Microscopy (BAM), X-Ray Reflectivity (XRR) and Grazing Incident X-ray Diffraction (GIXD). Among the usual phases described in the generic phase diagram of small head group molecules, one observes an unexpected reversible transition from an ordered condensed phase to a disordered one upon increasing the surface pressure. We postulate that the origin of this unusual, unprecedented transition results from the competition between the interactions between the diacetylene blocks in the hydrophobic chain and the hydrogen bonds between head-groups and water.
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000461751 7001_ $$00000-0002-5392-7147$$aSpagnoli, Sylvie$$b1
000461751 7001_ $$0P:(DE-H253)PIP1009721$$aFauré, Marie-Claude$$b2
000461751 7001_ $$00000-0002-2908-264X$$aAllain, Clémence$$b3
000461751 7001_ $$00000-0002-3933-9744$$aCoasne, Benoit$$b4
000461751 7001_ $$0P:(DE-HGF)0$$aMalinge, Jérémy$$b5
000461751 7001_ $$0P:(DE-H253)PIP1014115$$aShen, Chen$$b6$$udesy
000461751 7001_ $$00000-0003-3394-6508$$aFontaine, Philippe$$b7
000461751 7001_ $$0P:(DE-H253)PIP1008268$$aGoldmann, Michel$$b8$$eCorresponding author
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