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| 001 | 460397 | ||
| 005 | 20250724175535.0 | ||
| 024 | 7 | _ | |a 10.3390/molecules26133920 |2 doi |
| 024 | 7 | _ | |a 1420-3049 |2 ISSN |
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| 100 | 1 | _ | |a Weber, Martin |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex |
| 260 | _ | _ | |a Basel |c 2021 |b MDPI |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a By reacting [{Cp‴Fe(CO)2}2(µ,η1:1-P4)] (1) with in situ generated phosphenium ions [Ph2P][A] ([A]− = [OTf]− = [O3SCF3]−, [PF6]−), a mixture of two main products of the composition [{Cp‴Fe(CO)2}2(µ,η1:1-P5(C6H5)2)][PF6] (2a and 3a) could be identified by extensive 31P NMR spectroscopic studies at 193 K. Compound 3a was also characterized by X-ray diffraction analysis, showing the rarely observed bicyclo[2.1.0]pentaphosphapentane unit. At room temperature, the novel compound [{Cp‴Fe}(µ,η4:1-P5Ph2){Cp‴(CO)2Fe}][PF6] (4) is formed by decarbonylation. Reacting 1 with in situ generated diphenyl arsenium ions gives short-lived intermediates at 193 K which disproportionate at room temperature into tetraphenyldiarsine and [{Cp‴Fe(CO)2}4(µ4,η1:1:1:1-P8)][OTf]2 (5) containing a tetracyclo[3.3.0.02,7.03,6]octaphosphaoctane ligand. |
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| 700 | 1 | _ | |a Balázs, Gábor |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Virovets, Alexandr |0 P:(DE-H253)PIP1026845 |b 2 |
| 700 | 1 | _ | |a Peresypkina, Eugenia |0 P:(DE-H253)PIP1027099 |b 3 |
| 700 | 1 | _ | |a Scheer, Manfred |0 P:(DE-H253)PIP1027085 |b 4 |e Corresponding author |
| 773 | _ | _ | |a 10.3390/molecules26133920 |g Vol. 26, no. 13, p. 3920 - |0 PERI:(DE-600)2008644-1 |n 13 |p 3920 (1-13) |t Molecules |v 26 |y 2021 |x 1420-3049 |
| 856 | 4 | _ | |y OpenAccess |u https://bib-pubdb1.desy.de/record/460397/files/molecules-26-03920-v2.pdf |
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