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@ARTICLE{Becher:459810,
author = {Becher, Johannes and Weber, Sebastian and Ferreira Sanchez,
Dario and Doronkin, Dmitry and Garrevoet, Jan and
Falkenberg, Gerald and Motta Meira, Debora and Pascarelli,
Sakura and Grunwaldt, Jan-Dierk and Sheppard, Thomas L.},
title = {{S}ample {E}nvironment for {O}perando {H}ard {X}-ray
{T}omography—{A}n {E}nabling {T}echnology for {M}ultimodal
{C}haracterization in {H}eterogeneous {C}atalysis},
journal = {Catalysts},
volume = {11},
number = {4},
issn = {2073-4344},
address = {Basel},
publisher = {MDPI},
reportid = {PUBDB-2021-02756},
pages = {459 (1-18)},
year = {2021},
abstract = {Structure–activity relations in heterogeneous catalysis
can be revealed through in situ and operando measurements of
catalysts in their active state. While hard X-ray tomography
is an ideal method for non-invasive, multimodal 3D
structural characterization on the micron to nm scale,
performing tomography under controlled gas and temperature
conditions is challenging. Here, we present a flexible
sample environment for operando hard X-ray tomography at
synchrotron radiation sources. The setup features are
discussed, with demonstrations of operando powder X-ray
diffraction tomography (XRD-CT) and energy-dispersive
tomographic X-ray absorption spectroscopy (ED-XAS-CT).
Catalysts for CO$_2$ methanation and partial oxidation of
methane are shown as case studies. The setup can be adapted
for different hard X-ray microscopy, spectroscopy, or
scattering synchrotron radiation beamlines, is compatible
with absorption, diffraction, fluorescence, and
phase-contrast imaging, and can operate with scanning
focused beam or full-field acquisition mode. We present an
accessible methodology for operando hard X-ray tomography
studies, which offer a unique source of 3D spatially
resolved characterization data unavailable to contemporary
methods.},
cin = {FS-PETRA / FS-PS / KIT / FS-PET-S},
ddc = {540},
cid = {I:(DE-H253)FS-PETRA-20140814 / I:(DE-H253)FS-PS-20131107 /
I:(DE-H253)KIT-20130928 / I:(DE-H253)FS-PET-S-20190712},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
FS-Proposal: I-20191105 (I-20191105) / FS-Proposal:
I-20190299 (I-20190299)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20191105 / G:(DE-H253)I-20190299},
experiment = {EXP:(DE-H253)P-P06-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000642878200001},
doi = {10.3390/catal11040459},
url = {https://bib-pubdb1.desy.de/record/459810},
}