TY  - JOUR
AU  - Peresypkina, Eugenia
AU  - Grill, Kevin
AU  - Hiltl, Barbara
AU  - Virovets, Alexandr
AU  - Kremer, Werner
AU  - Hilgert, Jan
AU  - Tremel, Wolfgang
AU  - Scheer, Manfred
TI  - Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies
JO  - Angewandte Chemie / International edition
VL  - 60
IS  - 21
SN  - 1521-3773
CY  - Weinheim
PB  - Wiley-VCH
M1  - PUBDB-2021-02272
SP  - 12132 - 12142
PY  - 2021
AB  - One-pot self-assembly reactions of the polyphosphoruscomplex [Cp*Fe(η<sup>5</sup>-P<sub>5</sub>)] (A), a coinage metal saltAgSbF<sub>6</sub>, and flexible aliphatic dinitriles NC(CH<sub>2</sub>)<sub>x</sub>CN (x=1–10) yield 1D, 2D, and 3D coordination polymers. The sevenmemberedbackbone of the dinitrile was experimentally foundas the borderline for the self-assembly system furnishingproducts of different kinds. At x<7, various rather simplepolymers are exclusively formed possessing either 0D or 1DAg/A structural motifs connected by dinitrile spacers, while at x ≥ +7, the self-assembly switches to unprecedented extraordinary3D networks of nano-sized host–guest assemblies(SbF<sub>6</sub>)@[(A)<sub>9</sub>Ag<sub>11</sub>]<sup>11+</sup> (x=7) or (A)@[(A)<sub>12</sub>Ag<sub>12</sub>]<sup>12+</sup> (x=8–10) linked by dinitriles. The polycationic nodes represent thefirst superspheres based on A and silver and are host–guestable. All products are characterized by NMR spectroscopy,mass spectrometry, and single-crystal X-ray diffraction. Theassemblies [(A)<sub>12</sub>Ag<sub>12</sub>]<sup>12+</sup> were visualized by transmissionelectron microscopy.  
LB  - PUB:(DE-HGF)16
C6  - pmid:33686782
UR  - <Go to ISI:>//WOS:000646323700001
DO  - DOI:10.1002/anie.202103178
UR  - https://bib-pubdb1.desy.de/record/458619
ER  -