%0 Journal Article
%A Peresypkina, Eugenia
%A Grill, Kevin
%A Hiltl, Barbara
%A Virovets, Alexandr
%A Kremer, Werner
%A Hilgert, Jan
%A Tremel, Wolfgang
%A Scheer, Manfred
%T Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies
%J Angewandte Chemie / International edition
%V 60
%N 21
%@ 1521-3773
%C Weinheim
%I Wiley-VCH
%M PUBDB-2021-02272
%P 12132 - 12142
%D 2021
%X One-pot self-assembly reactions of the polyphosphoruscomplex [Cp*Fe(η<sup>5</sup>-P<sub>5</sub>)] (A), a coinage metal saltAgSbF<sub>6</sub>, and flexible aliphatic dinitriles NC(CH<sub>2</sub>)<sub>x</sub>CN (x=1–10) yield 1D, 2D, and 3D coordination polymers. The sevenmemberedbackbone of the dinitrile was experimentally foundas the borderline for the self-assembly system furnishingproducts of different kinds. At x<7, various rather simplepolymers are exclusively formed possessing either 0D or 1DAg/A structural motifs connected by dinitrile spacers, while at x ≥ +7, the self-assembly switches to unprecedented extraordinary3D networks of nano-sized host–guest assemblies(SbF<sub>6</sub>)@[(A)<sub>9</sub>Ag<sub>11</sub>]<sup>11+</sup> (x=7) or (A)@[(A)<sub>12</sub>Ag<sub>12</sub>]<sup>12+</sup> (x=8–10) linked by dinitriles. The polycationic nodes represent thefirst superspheres based on A and silver and are host–guestable. All products are characterized by NMR spectroscopy,mass spectrometry, and single-crystal X-ray diffraction. Theassemblies [(A)<sub>12</sub>Ag<sub>12</sub>]<sup>12+</sup> were visualized by transmissionelectron microscopy.  
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:33686782
%U <Go to ISI:>//WOS:000646323700001
%R 10.1002/anie.202103178
%U https://bib-pubdb1.desy.de/record/458619