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@ARTICLE{Heinl:458618,
      author       = {Heinl, Claudia and Peresypkina, Eugenia and Balázs, Gábor
                      and Mädl, Eric and Virovets, Alexandr and Scheer, Manfred},
      title        = {{T}he {M}issing {P}arent {C}ompound
                      $[({C}_{5}{H}_{5}){F}e(η^{5}‐{P}_{5})]$: {S}ynthesis,
                      {C}haracterization, {C}oordination {B}ehavior and
                      {E}ncapsulation},
      journal      = {Chemistry - a European journal},
      volume       = {27},
      number       = {27},
      issn         = {1521-3765},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2021-02271},
      pages        = {7542 - 7548},
      year         = {2021},
      abstract     = {The so far missing parent compound of the large family of
                      pentaphosphaferrocenes
                      [(C$_{5}$H$_{5}$)Fe($η^{5}‐P_{5})]$ (1 b) was
                      synthesized by the thermolysis of [CpFe(CO)$_2$]$_2$ with
                      P$_4$ using the very high-boiling solvent
                      diisopropylbenzene. It was comprehensively characterized by,
                      inter alia, NMR spectroscopy, single crystal X-ray structure
                      analysis, cyclic voltammetry and DFT computations. Moreover,
                      its coordination behavior towards CuI halides was explored,
                      revealing the unprecedented 2D polymeric networks
                      [{CpFe($η^{5:1:1:1:1}$-P$_5$)}Cu$_2$(μ-X)$_2$]$_n$ (2 a:
                      X=Cl, 2 b: X=Br) and
                      [{CpFe($η^{5:1:1}$-P$_5$)}Cu(μ-I)]$_n$ (3) and even the
                      first cyclo-P5-containing 3D coordination polymer
                      [{CpFe($η^{5:1:1}$-P$_5$)}Cu(μ-I)]$_n$ (4). The sandwich
                      complex 1 b can also be incorporated in nano-sized
                      supramolecules based on [Cp*Fe($η^5 -P_5$)] (1 a) and CuX
                      (X=Cl, Br, I): [CpFe($η^5 -P_5$)]@[{Cp*Fe($η^5
                      -P_5$)}$_{12}$(CuX)$_{20-n}$] (5 a: X=Cl, n=2.4; 5 b:
                      X=Br, n=2.4; 5 c: X=I, n=0.95). Thereby, the formation of
                      the CuI-containing fullerene-like sphere 5 c is found for
                      the first time.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20160654
                      (I-20160654)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20160654},
      experiment   = {EXP:(DE-H253)P-P11-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:33543820},
      UT           = {WOS:000627477800001},
      doi          = {10.1002/chem.202100203},
      url          = {https://bib-pubdb1.desy.de/record/458618},
}