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@ARTICLE{Arenas:458206,
author = {Arenas, Benjamin and Fatima, Mariyam and Pérez, Cristóbal
and Fischer, Sophie and Steber, Amanda L. and Schnell,
Melanie},
title = {{F}acilitating {I}nterstellar {S}earches for {S}imple
{A}mino {A}lcohols with {A}ccurate {R}est {F}requencies into
the {M}illimeter-wave {R}egime: {A}laninol, {V}alinol, and
{L}eucinol},
journal = {The astrophysical journal / 2},
volume = {912},
number = {2},
issn = {0004-637X},
address = {Chicago, Ill. [u.a.]},
publisher = {Univ.},
reportid = {PUBDB-2021-02190},
pages = {90},
year = {2021},
abstract = {The detection of larger complex organic molecules, such as
molecules consisting of several functional groups or those
which show conformational flexibility, in the interstellar
medium could lead to insights into the availability of
biomolecules in space. We present the rotational
spectroscopic study of three amino alcohols: alaninol,
valinol, and leucinol. The spectra were recorded over the
2–110 GHz region, which included the utilization of a
newly developed instrument operating between 18–26 GHz. We
report accurately determined line lists, rotational
constants, centrifugal distortion constants, and nuclear
quadrupole coupling constants for two conformers of
alaninol, four conformers of valinol, and three conformers
of leucinol, as well as for several singly substituted
heavy-atom isotopologues, which also provide structural
insights. Further, a number of spectra of vibrationally
excited states were assigned, and the associated motions
were revealed with anharmonic frequency calculations.
Accurate predictions of rotational transitions into the
millimeter-wave regime for all species were made,
facilitating searches for these complex molecules by
observational facilities such as ALMA. Their detection would
establish a new family of interstellar molecules.},
cin = {FS-SMP / CFEL-SDCCM},
ddc = {520},
cid = {I:(DE-H253)FS-SMP-20171124 /
I:(DE-H253)CFEL-SDCCM-20160915},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / ASTROROT - Unraveling interstellar chemistry
with broadband microwave spectroscopy and next-generation
telescope arrays (638027)},
pid = {G:(DE-HGF)POF4-631 / G:(EU-Grant)638027},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000648828300001},
doi = {10.3847/1538-4357/abe94c},
url = {https://bib-pubdb1.desy.de/record/458206},
}