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| 001 | 458176 | ||
| 005 | 20250724175447.0 | ||
| 024 | 7 | _ | |2 doi |a 10.1021/acs.inorgchem.1c00494 |
| 024 | 7 | _ | |2 ISSN |a 0020-1669 |
| 024 | 7 | _ | |2 ISSN |a 1520-510X |
| 024 | 7 | _ | |2 pmid |a pmid:33830751 |
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| 037 | _ | _ | |a PUBDB-2021-02179 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Brake, Helena |b 0 |
| 245 | _ | _ | |a Au-Containing Coordination Polymers Based on Polyphosphorus Ligand Complexes |
| 260 | _ | _ | |a Washington, DC |b American Chemical Society |c 2021 |
| 336 | 7 | _ | |2 DRIVER |a article |
| 336 | 7 | _ | |2 DataCite |a Output Types/Journal article |
| 336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1629378269_28308 |
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| 500 | _ | _ | |a Waiting for fulltext |
| 520 | _ | _ | |a Whereas the self-assembly of pentaphosphaferrocenes [Cp$^R$Fe(η$^5$-P$_5$)] (Cp$^R$ = Cp*, Cp$^×$, and Cp$^{Bn}$) with Cu and Ag salts has been well-studied in the past, the coordination chemistry toward Au complexes has been left untouched so far. Herein, the results of the self-assembly processes of [Cp$^R$Fe($η^5$-P$_5$)] with Au salts of different anions (GaCl$_4$$^–$, SbF$_6$$^–$, and Al(OC(CF$_3$)$_3$)$_4$ (TEF$^–$)) are reported. Next to a variety of molecular coordination products, the first coordination polymers based on polyphosphorus ligand complexes and Au salts are also obtained. Thereby, a 2D coordination polymer comprising metal vacancies is isolated. In all products, the Au centers are coordinated in a linear or a trigonal planar environment. In solution, highly dynamic processes are observed. Variable-temperature NMR spectroscopy, solid-state NMR spectroscopy, and X-ray powder diffraction were applied to gain further insight into selected coordination compounds. |
| 536 | _ | _ | |0 G:(DE-HGF)POF4-6G3 |a 6G3 - PETRA III (DESY) (POF4-6G3) |c POF4-6G3 |f POF IV |x 0 |
| 536 | _ | _ | |0 G:(DE-H253)I-20180967 |a FS-Proposal: I-20180967 (I-20180967) |c I-20180967 |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
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| 700 | 1 | _ | |0 P:(DE-H253)PIP1027099 |a Peresypkina, Eugenia |b 1 |
| 700 | 1 | _ | |0 P:(DE-H253)PIP1026845 |a Virovets, Alexandr |b 2 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Kremer, Werner |b 3 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Klimas, Christian |b 4 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Schwarzmaier, Christoph |b 5 |
| 700 | 1 | _ | |0 P:(DE-H253)PIP1027085 |a Scheer, Manfred |b 6 |e Corresponding author |
| 773 | _ | _ | |0 PERI:(DE-600)1484438-2 |a 10.1021/acs.inorgchem.1c00494 |g Vol. 60, no. 8, p. 6027 - 6039 |n 8 |p 6027 - 6039 |t Inorganic chemistry |v 60 |x 1520-510X |y 2021 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/458176/files/ic1c00494_si_001.pdf |y Restricted |
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