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@ARTICLE{Brake:458176,
author = {Brake, Helena and Peresypkina, Eugenia and Virovets,
Alexandr and Kremer, Werner and Klimas, Christian and
Schwarzmaier, Christoph and Scheer, Manfred},
title = {{A}u-{C}ontaining {C}oordination {P}olymers {B}ased on
{P}olyphosphorus {L}igand {C}omplexes},
journal = {Inorganic chemistry},
volume = {60},
number = {8},
issn = {1520-510X},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {PUBDB-2021-02179},
pages = {6027 - 6039},
year = {2021},
note = {Waiting for fulltext},
abstract = {Whereas the self-assembly of pentaphosphaferrocenes
[Cp$^R$Fe(η$^5$-P$_5$)] (Cp$^R$ = Cp*, Cp$^×$, and
Cp$^{Bn}$) with Cu and Ag salts has been well-studied in the
past, the coordination chemistry toward Au complexes has
been left untouched so far. Herein, the results of the
self-assembly processes of [Cp$^R$Fe($η^5$-P$_5$)] with Au
salts of different anions (GaCl$_4$$^–$, SbF$_6$$^–$,
and Al(OC(CF$_3$)$_3$)$_4$ (TEF$^–$)) are reported. Next
to a variety of molecular coordination products, the first
coordination polymers based on polyphosphorus ligand
complexes and Au salts are also obtained. Thereby, a 2D
coordination polymer comprising metal vacancies is isolated.
In all products, the Au centers are coordinated in a linear
or a trigonal planar environment. In solution, highly
dynamic processes are observed. Variable-temperature NMR
spectroscopy, solid-state NMR spectroscopy, and X-ray powder
diffraction were applied to gain further insight into
selected coordination compounds.},
cin = {DOOR ; HAS-User},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20180967
(I-20180967)},
pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20180967},
experiment = {EXP:(DE-H253)P-P24-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:33830751},
UT = {WOS:000642344900064},
doi = {10.1021/acs.inorgchem.1c00494},
url = {https://bib-pubdb1.desy.de/record/458176},
}