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@MISC{Zak:457238,
author = {Zak, Emil},
title = {{C}hiral molecules detection - preface to a special issue
in '{S}ymmetry' {J}ournal ({MDPI} publisher)},
reportid = {PUBDB-2021-01921},
year = {2021},
note = {This is a short description for a planned special issue
'chiral molecules detection' in the Symmetry Journal (MDPI).
The leaflet is going to be visible on the publisher's
website. I was invited to guest edit the special issue.},
abstract = {Chirality is prevalent in the natural environment. Systems
of biological significance more often than not exist in two
enantiomeric (mirror-image) forms, which are
non-superimposableby rotations and translations in space.
Dating back to Pasteur, there has been a long and formidable
history of methods for determining the absolute handedness
of chemicals and the enantiomeric excess in mixtures of
chiral compounds.Several modernly expanded techniques for
studying chirality had already given a paramount impact on
chemistry, biology and medicine. Circular dichroism
spectroscopy, microwave three-wave mixing, Coulomb explosion
especially combined with COLTRIMS (cold target recoil ion
momentum spectroscopy), or modern table-top experiments
utilizing the photo-electron circular dichroism, are only
few out of many methods used to probe chirality in the gas
phase molecules.Rapid development of the femtosecond and
attosecond laser technology allowed to probe even deeper
into the realm where the molecular chirality emerges - on
the time-scale of the electronic motions. We therefore may
at least consider pondering on the non-static nature of
chirality, studying which has recently become a laboratory
reality. This exciting time, in which the experiment
tentatively reaches into the molecular frame of chiral
molecules at (sub-)femtosecond and (sub-)angstroms
resolution, must bring new insights and discoveries.Past two
decades have been a witness to a pursuit in theoretical
methods as well, which parallel to the experiment, aim at
underpinning the nature of chirality by proposing ever new
and more sensitive probes of chirality. Some of the
theoretical methods present a significant computational
challenge, which triggers algorithmic developments in
quantum calculations.We welcome theoretical as well as
experimental contributions covering concepts and techniques
not only for measuring the enantiomeric excess in mixtures
of chiral molecules, but also approaches to discriminate
chiral species, separate them or to unravel the role of the
nuclear and electronic motion in interacting chiral
systems.},
cin = {FS-CFEL-1 / FS-CFEL-CMI},
cid = {I:(DE-H253)FS-CFEL-1-20120731 /
I:(DE-H253)FS-CFEL-CMI-20220405},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631)},
pid = {G:(DE-HGF)POF4-631},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)4},
url = {https://bib-pubdb1.desy.de/record/457238},
}