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@ARTICLE{Giuntini:457042,
      author       = {Giuntini, Diletta and Davydok, Anton and Blankenburg, Malte
                      and Domènech, Berta and Bor, Büsra and Li, Mingjing and
                      Scheider, Ingo and Krywka, Christina and Mueller, Martin and
                      Schneider, Gerold A.},
      title        = {{D}eformation {B}ehavior of {C}ross-{L}inked
                      {S}upercrystalline {N}anocomposites: {A}n in {S}itu
                      {SAXS}/{WAXS} {S}tudy during {U}niaxial {C}ompression},
      journal      = {Nano letters},
      volume       = {21},
      number       = {7},
      issn         = {1530-6992},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PUBDB-2021-01808},
      pages        = {2891 - 2897},
      year         = {2021},
      abstract     = {With the ever-expanding functional applications of
                      supercrystalline nanocomposites (a relatively new category
                      of materials consisting of organically functionalized
                      nanoparticles arranged into periodic structures), it becomes
                      necessary to ensure their structural stability and
                      understand their deformation and failure mechanisms.
                      Inducing the cross-linking of the functionalizing organic
                      ligands, for instance, leads to a remarkable enhancement of
                      the nanocomposites’ mechanical properties. It is however
                      still unknown how the cross-linked organic phase
                      redistributes applied loads, how the supercrystalline
                      lattice accommodates the imposed deformations, and thus in
                      general what phenomena govern the overall material’s
                      mechanical response. This work elucidates these aspects for
                      cross-linked supercrystalline nanocomposites through an in
                      situ small- and wide-angle X-ray scattering study combined
                      with uniaxial pressing. Because of this loading condition,
                      it emerges that the cross-linked ligands effectively carry
                      and distribute loads homogeneously throughout the
                      nanocomposites, while the superlattice deforms via rotation,
                      slip, and local defects generation.},
      cin          = {DOOR ; HAS-User / HZG},
      ddc          = {660},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)HZG-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P03-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:33749275},
      UT           = {WOS:000641160500026},
      doi          = {10.1021/acs.nanolett.0c05041},
      url          = {https://bib-pubdb1.desy.de/record/457042},
}