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000456667 1001_ $$0P:(DE-H253)PIP1082600$$aAlizadehfanaloo, Saba$$b0$$eCorresponding author$$udesy
000456667 245__ $$aTracking Dynamic Structural Changes in Catalysis by Rapid 2D-XANES Microscopy
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000456667 520__ $$aMany processes and materials in heterogeneous catalysis undergo dynamic structural changes depending on their chemical environment. Monitoring such dynamic changes can be challenging using conventional spectroscopic characterization tools, due to the high time resolution required. Here, a high-resolution 2D X-ray camera operating at 50 Hz full-frame rate was synchronized with a QEXAFS monochromator, enabling rapid spectro-microscopic imaging with chemical contrast over individual pixels. This was used to monitor chemical gradients within a model Pt/Al2O3 catalyst during catalytic partial oxidation of methane to synthesis gas. The transition from methane combustion (partly oxidized Pt) to combustion-reforming and partial oxidation (fully reduced Pt) was observed by a characteristic reduction front, which progressed from the end of the catalyst bed towards its beginning on the second time scale. The full-field QEXAFS imaging method applied here allows acquisition of entire XANES spectra `on the fly' in a rapid and spatially resolved manner. The combination of high spatial and temporal resolution with spectroscopic data offers new opportunities for observing dynamic processes in catalysts and other functional materials at work. The methodology is flexible and can be applied at beamlines equipped with a QEXAFS or other fast-scanning monochromators and a suitable sample environment for gas phase analytics to allow for catalytic studies at the same time.
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000456667 7001_ $$0P:(DE-H253)PIP1013228$$aGarrevoet, Jan$$b1$$udesy
000456667 7001_ $$0P:(DE-H253)PIP1023668$$aSeyrich, Martin$$b2$$udesy
000456667 7001_ $$0P:(DE-H253)PIP1020056$$aMurzin, Vadim$$b3
000456667 7001_ $$0P:(DE-H253)PIP1031661$$aBecher, Johannes$$b4
000456667 7001_ $$0P:(DE-H253)PIP1017208$$aDoronkin, Dmitry$$b5
000456667 7001_ $$0P:(DE-H253)PIP1024276$$aSheppard, Thomas$$b6
000456667 7001_ $$0P:(DE-H253)PIP1008522$$aGrunwaldt, Jan-Dierk$$b7
000456667 7001_ $$0P:(DE-H253)PIP1008438$$aSchroer, Christian$$b8$$udesy
000456667 7001_ $$0P:(DE-H253)PIP1011060$$aSchropp, Andreas$$b9$$eCorresponding author$$udesy
000456667 773__ $$0PERI:(DE-600)2021413-3$$a10.1107/S1600577521007074$$gVol. 28, no. 5, p. 1518 - 1527$$n5$$p1518 - 1527$$tJournal of synchrotron radiation$$v28$$x1600-5775$$y2021
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