000456183 001__ 456183
000456183 005__ 20250716150535.0
000456183 0247_ $$2doi$$a10.1063/5.0029792
000456183 0247_ $$2ISSN$$a0021-9606
000456183 0247_ $$2ISSN$$a1089-7690
000456183 0247_ $$2ISSN$$a1520-9032
000456183 0247_ $$2altmetric$$aaltmetric:90914800
000456183 0247_ $$2pmid$$apmid:33607914
000456183 0247_ $$2WOS$$aWOS:000630521200001
000456183 0247_ $$2datacite_doi$$a10.3204/PUBDB-2021-01390
000456183 0247_ $$2openalex$$aopenalex:W3132369647
000456183 037__ $$aPUBDB-2021-01390
000456183 041__ $$aEnglish
000456183 082__ $$a530
000456183 1001_ $$0P:(DE-H253)PIP1087238$$aSaribal, Cem$$b0
000456183 245__ $$aDetecting handedness of spatially oriented molecules by Coulomb explosion imaging
000456183 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2021
000456183 3367_ $$2DRIVER$$aarticle
000456183 3367_ $$2DataCite$$aOutput Types/Journal article
000456183 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1718800225_3742813
000456183 3367_ $$2BibTeX$$aARTICLE
000456183 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000456183 3367_ $$00$$2EndNote$$aJournal Article
000456183 520__ $$aWe present a new technique for detecting chirality in the gas phase: Chiral molecules are spatially aligned in three dimensions by a moderately strong elliptically polarized laser field. The momentum distributions of the charged fragments, produced by laser-induced Coulomb explosion, show distinct three-dimensional orientation of the enantiomers when the laser polarization ellipse is rotated by a non-right angle with respect to the norm vector of the detector plane. The resulting velocity-map-image asymmetry is directly connected to the enantiomeric excess and to the absolute handedness of molecules. We demonstrated our scheme computationally for camphor (C10H16O), with its methyl groups as marker fragments, using quantum-mechanical simulations geared toward experimentally feasible conditions. Computed sensitivity to enantiomeric excess is comparable to other modern chiroptical approaches. The present method can be readily optimized for any chiral molecule with an anisotropic polarizability tensor by adjusting the polarization state and intensity profile of the laser field.
000456183 536__ $$0G:(DE-HGF)POF4-631$$a631 - Matter – Dynamics, Mechanisms and Control (POF4-631)$$cPOF4-631$$fPOF IV$$x0
000456183 536__ $$0G:(GEPRIS)390715994$$aDFG project 390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994)$$c390715994$$x1
000456183 536__ $$0G:(GEPRIS)194651731$$aDFG project 194651731 - EXC 1074: Hamburger Zentrum für ultraschnelle Beobachtung (CUI): Struktur, Dynamik und Kontrolle von Materie auf atomarer Skala (194651731)$$c194651731$$x2
000456183 536__ $$0G:(GEPRIS)255652344$$aDFG project 255652344 - SPP 1840: Quantum Dynamics in Tailored Intense Fields (QUTIF) (255652344)$$c255652344$$x3
000456183 536__ $$0G:(DE-HGF)2018_Ex-Net-0002-Phase2-3$$aEx-Net-0002-Phase2-3 - Advanced Imaging of Matter: Structure, Dynamics and Control on the Atomic Scale - AIM (2018_Ex-Net-0002-Phase2-3)$$c2018_Ex-Net-0002-Phase2-3$$x4
000456183 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000456183 693__ $$0EXP:(DE-MLZ)NOSPEC-20140101$$5EXP:(DE-MLZ)NOSPEC-20140101$$eNo specific instrument$$x0
000456183 7001_ $$0P:(DE-HGF)0$$aOwens, Alec$$b1
000456183 7001_ $$0P:(DE-H253)PIP1031546$$aYachmenev, Andrey$$b2$$eCorresponding author$$udesy
000456183 7001_ $$0P:(DE-H253)PIP1012175$$aKüpper, Jochen$$b3
000456183 773__ $$0PERI:(DE-600)1473050-9$$a10.1063/5.0029792$$gVol. 154, no. 7, p. 071101 -$$n7$$p071101$$tThe journal of chemical physics$$v154$$x1089-7690$$y2021
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/5.0029792%282%29.pdf$$yPublished on 2021-02-18. Available in OpenAccess from 2022-02-18.
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/main%20file.pdf$$yPublished on 2021-02-18. Available in OpenAccess from 2022-02-18.
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/teaser%20image.gif
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/5.0029792%282%29.pdf?subformat=pdfa$$xpdfa$$yPublished on 2021-02-18. Available in OpenAccess from 2022-02-18.
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/main%20file.pdf?subformat=pdfa$$xpdfa$$yPublished on 2021-02-18. Available in OpenAccess from 2022-02-18.
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/teaser%20image.gif?subformat=icon$$xicon
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/teaser%20image.jpg?subformat=icon-180$$xicon-180
000456183 8564_ $$uhttps://bib-pubdb1.desy.de/record/456183/files/teaser%20image.jpg?subformat=icon-700$$xicon-700
000456183 909CO $$ooai:bib-pubdb1.desy.de:456183$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000456183 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1087238$$aCentre for Free-Electron Laser Science$$b0$$kCFEL
000456183 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1087238$$aExternal Institute$$b0$$kExtern
000456183 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1031546$$aDeutsches Elektronen-Synchrotron$$b2$$kDESY
000456183 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1031546$$aCentre for Free-Electron Laser Science$$b2$$kCFEL
000456183 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1012175$$aDeutsches Elektronen-Synchrotron$$b3$$kDESY
000456183 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1012175$$aCentre for Free-Electron Laser Science$$b3$$kCFEL
000456183 9131_ $$0G:(DE-HGF)POF4-631$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vMatter – Dynamics, Mechanisms and Control$$x0
000456183 9130_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6211$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000456183 9141_ $$y2021
000456183 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0530$$2StatID$$aEmbargoed OpenAccess
000456183 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000456183 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ CHEM PHYS : 2019$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0430$$2StatID$$aNational-Konsortium$$d2021-02-02$$wger
000456183 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0320$$2StatID$$aDBCoverage$$bPubMed Central$$d2021-02-02
000456183 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2021-02-02$$wger
000456183 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2021-02-02
000456183 9201_ $$0I:(DE-H253)FS-CFEL-1-20120731$$kFS-CFEL-1$$lCFEL-Coherent X-Ray Imaging$$x0
000456183 9201_ $$0I:(DE-H253)FS-CFEL-CMI-20220405$$kFS-CFEL-CMI$$lCFEL-CMI$$x1
000456183 9201_ $$0I:(DE-H253)UNI_CUI-20121230$$kUNI/CUI$$lbeauftragt von UNI$$x2
000456183 9201_ $$0I:(DE-H253)UNI_EXP-20120731$$kUNI/EXP$$lUni Hamburg / Experimentalphysik$$x3
000456183 980__ $$ajournal
000456183 980__ $$aVDB
000456183 980__ $$aI:(DE-H253)FS-CFEL-1-20120731
000456183 980__ $$aI:(DE-H253)FS-CFEL-CMI-20220405
000456183 980__ $$aI:(DE-H253)UNI_CUI-20121230
000456183 980__ $$aI:(DE-H253)UNI_EXP-20120731
000456183 980__ $$aUNRESTRICTED
000456183 9801_ $$aFullTexts