Home > Publications database > Polyphenylene as an Active Support for Ru-Catalyzed Hydrogenolysis of 5-Hydroxymethylfurfural > print

001     455776
005     20210901211814.0
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082 _ _ |a 600
100 1 _ |a Wang, Qiming
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245 _ _ |a Polyphenylene as an Active Support for Ru-Catalyzed Hydrogenolysis of 5-Hydroxymethylfurfural
260 _ _ |a Washington, DC
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520 _ _ |a Selective transformation of biomass feedstocks to platform molecules is a key pursuit for sustainable chemical production. Compared to petrochemical processes, biomass transformation requires the defunctionalization of highly polar molecules at relatively low temperatures. As a result, catalysts based on functional organic polymers may play a prominent role. Targeting the hydrogenolysis of the platform chemical 5-hydroxymethylfurfural (5-HMF), here, we design a polyphenylene (PPhen) framework with purely sp2-hybridized carbons that can isolate 5-HMF via π−π stacking, preventing hemiacetal and humin formation. With good swellability, the PPhen framework here has successfully supported and dispersed seven types of metal particles via a newly developed swelling-impregnation method, including Ru, Pt, Au, Fe, Co, Ni, and Cu. Ru/PPhen is studied for 5-HMF hydrogenolysis, achieving a 92% yield of 2,5-dimethylfuran (DMF) under mild conditions, outperforming the state-of-the-art catalysts reported in the literature. In addition, PPhen helps perform a solventless reaction, achieving direct 5-HMF to DMF conversion in the absence of any liquid solvent or reagent. This approach in designing support−reactant/solvent/metal interactions will play an important role in surface catalysis
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700 1 _ |a Guan, Xuze
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700 1 _ |a Kang, Liqun
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700 1 _ |a Wang, Bolun
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700 1 _ |a Sheng, Lin
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700 1 _ |a Wang, Feng Ryan
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773 _ _ |a 10.1021/acsami.0c11888
|g Vol. 12, no. 48, p. 53712 - 53718
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|t ACS applied materials & interfaces
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|y 2020
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856 4 _ |u https://pubs.acs.org/doi/10.1021/acsami.0c11888
856 4 _ |u https://bib-pubdb1.desy.de/record/455776/files/PPhen_Ru_0921.pdf
|y Published on 2020-11-19. Available in OpenAccess from 2021-11-19.
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