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@ARTICLE{Wang:455776,
      author       = {Wang, Qiming and Guan, Xuze and Kang, Liqun and Wang, Bolun
                      and Sheng, Lin and Wang, Feng Ryan},
      title        = {{P}olyphenylene as an {A}ctive {S}upport for
                      {R}u-{C}atalyzed {H}ydrogenolysis of
                      5-{H}ydroxymethylfurfural},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {12},
      number       = {48},
      issn         = {1944-8252},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PUBDB-2021-01210},
      pages        = {53712 - 53718},
      year         = {2020},
      abstract     = {Selective transformation of biomass feedstocks to platform
                      molecules is a key pursuit for sustainable chemical
                      production. Compared to petrochemical processes, biomass
                      transformation requires the defunctionalization of highly
                      polar molecules at relatively low temperatures. As a result,
                      catalysts based on functional organic polymers may play a
                      prominent role. Targeting the hydrogenolysis of the platform
                      chemical 5-hydroxymethylfurfural (5-HMF), here, we design a
                      polyphenylene (PPhen) framework with purely sp2-hybridized
                      carbons that can isolate 5-HMF via π−π stacking,
                      preventing hemiacetal and humin formation. With good
                      swellability, the PPhen framework here has successfully
                      supported and dispersed seven types of metal particles via a
                      newly developed swelling-impregnation method, including Ru,
                      Pt, Au, Fe, Co, Ni, and Cu. Ru/PPhen is studied for 5-HMF
                      hydrogenolysis, achieving a $92\%$ yield of
                      2,5-dimethylfuran (DMF) under mild conditions, outperforming
                      the state-of-the-art catalysts reported in the literature.
                      In addition, PPhen helps perform a solventless reaction,
                      achieving direct 5-HMF to DMF conversion in the absence of
                      any liquid solvent or reagent. This approach in designing
                      support−reactant/solvent/metal interactions will play an
                      important role in surface catalysis},
      cin          = {DOOR ; HAS-User},
      ddc          = {600},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (POF3-622) / FS-Proposal: I-20190358 EC
                      (I-20190358-EC)},
      pid          = {G:(DE-HGF)POF3-6G3 / G:(DE-H253)I-20190358-EC},
      experiment   = {EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:33210901},
      UT           = {WOS:000596876400013},
      doi          = {10.1021/acsami.0c11888},
      url          = {https://bib-pubdb1.desy.de/record/455776},
}