TY  - JOUR
AU  - Wang, Qiming
AU  - Guan, Xuze
AU  - Kang, Liqun
AU  - Wang, Bolun
AU  - Sheng, Lin
AU  - Wang, Feng Ryan
TI  - Polyphenylene as an Active Support for Ru-Catalyzed Hydrogenolysis of 5-Hydroxymethylfurfural
JO  - ACS applied materials & interfaces
VL  - 12
IS  - 48
SN  - 1944-8252
CY  - Washington, DC
PB  - Soc.
M1  - PUBDB-2021-01210
SP  - 53712 - 53718
PY  - 2020
AB  - Selective transformation of biomass feedstocks to platform molecules is a key pursuit for sustainable chemical production. Compared to petrochemical processes, biomass transformation requires the defunctionalization of highly polar molecules at relatively low temperatures. As a result, catalysts based on functional organic polymers may play a prominent role. Targeting the hydrogenolysis of the platform chemical 5-hydroxymethylfurfural (5-HMF), here, we design a polyphenylene (PPhen) framework with purely sp2-hybridized carbons that can isolate 5-HMF via π−π stacking, preventing hemiacetal and humin formation. With good swellability, the PPhen framework here has successfully supported and dispersed seven types of metal particles via a newly developed swelling-impregnation method, including Ru, Pt, Au, Fe, Co, Ni, and Cu. Ru/PPhen is studied for 5-HMF hydrogenolysis, achieving a 92
LB  - PUB:(DE-HGF)16
C6  - pmid:33210901
UR  - <Go to ISI:>//WOS:000596876400013
DO  - DOI:10.1021/acsami.0c11888
UR  - https://bib-pubdb1.desy.de/record/455776
ER  -