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000455776 1001_ $$aWang, Qiming$$b0
000455776 245__ $$aPolyphenylene as an Active Support for Ru-Catalyzed Hydrogenolysis of 5-Hydroxymethylfurfural
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000455776 520__ $$aSelective transformation of biomass feedstocks to platform molecules is a key pursuit for sustainable chemical production. Compared to petrochemical processes, biomass transformation requires the defunctionalization of highly polar molecules at relatively low temperatures. As a result, catalysts based on functional organic polymers may play a prominent role. Targeting the hydrogenolysis of the platform chemical 5-hydroxymethylfurfural (5-HMF), here, we design a polyphenylene (PPhen) framework with purely sp2-hybridized carbons that can isolate 5-HMF via π−π stacking, preventing hemiacetal and humin formation. With good swellability, the PPhen framework here has successfully supported and dispersed seven types of metal particles via a newly developed swelling-impregnation method, including Ru, Pt, Au, Fe, Co, Ni, and Cu. Ru/PPhen is studied for 5-HMF hydrogenolysis, achieving a 92% yield of 2,5-dimethylfuran (DMF) under mild conditions, outperforming the state-of-the-art catalysts reported in the literature. In addition, PPhen helps perform a solventless reaction, achieving direct 5-HMF to DMF conversion in the absence of any liquid solvent or reagent. This approach in designing support−reactant/solvent/metal interactions will play an important role in surface catalysis
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000455776 7001_ $$aGuan, Xuze$$b1
000455776 7001_ $$aKang, Liqun$$b2
000455776 7001_ $$aWang, Bolun$$b3
000455776 7001_ $$aSheng, Lin$$b4
000455776 7001_ $$0P:(DE-H253)PIP1086043$$aWang, Feng Ryan$$b5$$eCorresponding author
000455776 773__ $$0PERI:(DE-600)2467494-1$$a10.1021/acsami.0c11888$$gVol. 12, no. 48, p. 53712 - 53718$$n48$$p53712 - 53718$$tACS applied materials & interfaces$$v12$$x1944-8252$$y2020
000455776 8564_ $$uhttps://pubs.acs.org/doi/10.1021/acsami.0c11888
000455776 8564_ $$uhttps://bib-pubdb1.desy.de/record/455776/files/PPhen_Ru_0921.pdf$$yPublished on 2020-11-19. Available in OpenAccess from 2021-11-19.
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