%0 Journal Article
%A Wang, Qiming
%A Guan, Xuze
%A Kang, Liqun
%A Wang, Bolun
%A Sheng, Lin
%A Wang, Feng Ryan
%T Polyphenylene as an Active Support for Ru-Catalyzed Hydrogenolysis of 5-Hydroxymethylfurfural
%J ACS applied materials & interfaces
%V 12
%N 48
%@ 1944-8252
%C Washington, DC
%I Soc.
%M PUBDB-2021-01210
%P 53712 - 53718
%D 2020
%X Selective transformation of biomass feedstocks to platform molecules is a key pursuit for sustainable chemical production. Compared to petrochemical processes, biomass transformation requires the defunctionalization of highly polar molecules at relatively low temperatures. As a result, catalysts based on functional organic polymers may play a prominent role. Targeting the hydrogenolysis of the platform chemical 5-hydroxymethylfurfural (5-HMF), here, we design a polyphenylene (PPhen) framework with purely sp2-hybridized carbons that can isolate 5-HMF via π−π stacking, preventing hemiacetal and humin formation. With good swellability, the PPhen framework here has successfully supported and dispersed seven types of metal particles via a newly developed swelling-impregnation method, including Ru, Pt, Au, Fe, Co, Ni, and Cu. Ru/PPhen is studied for 5-HMF hydrogenolysis, achieving a 92
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:33210901
%U <Go to ISI:>//WOS:000596876400013
%R 10.1021/acsami.0c11888
%U https://bib-pubdb1.desy.de/record/455776