000454844 001__ 454844
000454844 005__ 20250716150548.0
000454844 0247_ $$2doi$$a10.1038/s42004-021-00468-4
000454844 0247_ $$2datacite_doi$$a10.3204/PUBDB-2021-00777
000454844 0247_ $$2altmetric$$aaltmetric:101405700
000454844 0247_ $$2WOS$$aWOS:000626585700003
000454844 0247_ $$2openalex$$aopenalex:W3135428646
000454844 037__ $$aPUBDB-2021-00777
000454844 041__ $$aEnglish
000454844 082__ $$a540
000454844 1001_ $$0P:(DE-H253)PIP1023833$$aDomingos, Sérgio R.$$b0$$eCorresponding author
000454844 245__ $$aDynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
000454844 260__ $$a[London]$$bMacmillan Publishers Limited, part of Springer Nature$$c2021
000454844 3367_ $$2DRIVER$$aarticle
000454844 3367_ $$2DataCite$$aOutput Types/Journal article
000454844 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1623060721_16370
000454844 3367_ $$2BibTeX$$aARTICLE
000454844 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000454844 3367_ $$00$$2EndNote$$aJournal Article
000454844 520__ $$aChiral molecular recognition is a pivotal phenomenon in biomolecular science, governed by subtle balances of intermolecular forces that are difficult to quantify. Non-covalent interactions involving aromatic moieties are particularly important in this realm, as recurring motifs in biomolecular aggregation. In this work, we use high-resolution broadband rotational spectroscopy to probe the dynamic conformational landscape enclosing the self-pairing topologies of styrene oxide, a chiral aromatic system. We reach a definite assignment of four homochiral and two heterochiral dimers using auxiliary quantum chemistry calculations as well as structure-solving methods based on experimental isotopic information. A complete picture of the dimer conformational space is obtained, and plausible routes for conformational relaxation are derived. Molecular structures are discussed in terms of conformational flexibility, the concerted effort of weak intermolecular interactions, and their role in the expression of the molecular fit.
000454844 536__ $$0G:(DE-HGF)POF4-631$$a631 - Matter – Dynamics, Mechanisms and Control (POF4-631)$$cPOF4-631$$fPOF IV$$x0
000454844 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000454844 693__ $$0EXP:(DE-MLZ)NOSPEC-20140101$$5EXP:(DE-MLZ)NOSPEC-20140101$$eNo specific instrument$$x0
000454844 7001_ $$0P:(DE-H253)PIP1023832$$aPérez, Cristóbal$$b1
000454844 7001_ $$aKreienborg, Nora M.$$b2
000454844 7001_ $$00000-0002-4106-1905$$aMerten, Christian$$b3
000454844 7001_ $$0P:(DE-H253)PIP1013514$$aSchnell, Melanie$$b4$$eCorresponding author
000454844 773__ $$0PERI:(DE-600)2929562-2$$a10.1038/s42004-021-00468-4$$gVol. 4, no. 1, p. 32$$n1$$p32$$tCommunications chemistry$$v4$$x2399-3669$$y2021
000454844 8564_ $$uhttps://www.nature.com/articles/s42004-021-00468-4
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.pdf
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.gif?subformat=icon$$xicon
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.jpg?subformat=icon-1440$$xicon-1440
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.jpg?subformat=icon-180$$xicon-180
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.jpg?subformat=icon-640$$xicon-640
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/Admin-Domingos.pdf?subformat=pdfa$$xpdfa
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/s42004-021-00468-4.pdf$$yOpenAccess
000454844 8564_ $$uhttps://bib-pubdb1.desy.de/record/454844/files/s42004-021-00468-4.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000454844 8767_ $$8SN-2021-00401-b$$92021-06-18$$d2021-02-02$$eAPC$$jDEAL$$lSpringerNature$$zMS Einzelpreis per Rechnung erhalten SN-2021-00401-b
000454844 909CO $$ooai:bib-pubdb1.desy.de:454844$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire
000454844 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1023833$$aExternal Institute$$b0$$kExtern
000454844 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1023832$$aDeutsches Elektronen-Synchrotron$$b1$$kDESY
000454844 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1023832$$aCentre for Free-Electron Laser Science$$b1$$kCFEL
000454844 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1013514$$aDeutsches Elektronen-Synchrotron$$b4$$kDESY
000454844 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1013514$$aCentre for Free-Electron Laser Science$$b4$$kCFEL
000454844 9130_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6215$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000454844 9131_ $$0G:(DE-HGF)POF4-631$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lFrom Matter to Materials and Life$$vMatter – Dynamics, Mechanisms and Control$$x0
000454844 9141_ $$y2021
000454844 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-09-09
000454844 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000454844 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000454844 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Blind peer review$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-09-09
000454844 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-09-09
000454844 915pc $$0PC:(DE-HGF)0000$$2APC$$aAPC keys set
000454844 915pc $$0PC:(DE-HGF)0001$$2APC$$aLocal Funding
000454844 915pc $$0PC:(DE-HGF)0002$$2APC$$aDFG OA Publikationskosten
000454844 915pc $$0PC:(DE-HGF)0003$$2APC$$aDOAJ Journal
000454844 915pc $$0PC:(DE-HGF)0113$$2APC$$aDEAL: Springer Nature 2020
000454844 9201_ $$0I:(DE-H253)FS-SMP-20171124$$kFS-SMP$$lSpectroscopy of molecular processes$$x0
000454844 9201_ $$0I:(DE-H253)CFEL-SDCCM-20160915$$kCFEL-SDCCM$$lMPSD$$x1
000454844 980__ $$ajournal
000454844 980__ $$aVDB
000454844 980__ $$aUNRESTRICTED
000454844 980__ $$aI:(DE-H253)FS-SMP-20171124
000454844 980__ $$aI:(DE-H253)CFEL-SDCCM-20160915
000454844 980__ $$aAPC
000454844 9801_ $$aAPC
000454844 9801_ $$aFullTexts