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@ARTICLE{Zabilskiy:454742,
      author       = {Zabilskiy, Maxim and Arčon, Iztok and Djinović, Petar and
                      Tchernychova, Elena and Pintar, Albin},
      title        = {{I}n‐situ {XAS} study of catalytic {N}$_{2}${O}
                      decomposition over {C}u{O}/{C}e{O}$_{2}$ catalysts},
      journal      = {ChemCatChem},
      volume       = {13},
      number       = {7},
      issn         = {1867-3899},
      address      = {Weinheim},
      publisher    = {WILEY-VCH Verlag},
      reportid     = {PUBDB-2021-00706},
      pages        = {1814 - 1823},
      year         = {2021},
      abstract     = {We performed in‐situ XAS study of N$_{2}$O decomposition
                      over CuO/CeO$_{2}$ catalysts. The Cu K‐edge and Ce L$_{3}$
                      ‐edge XANES and EXAFS analyses revealed the dynamic and
                      crucial role of Cu$^{2+}$/Cu + and Ce$^{4+}$ /Ce$^{3+}$
                      ionic pairs during the catalytic reaction. We observed the
                      initial formation of reduced Cu + and Ce$^{3+}$ species
                      during activation in helium atmosphere at 400 °C, while
                      concentration of these species decreased significantly
                      during steady‐state nitrous oxide degradation reaction
                      (2500 ppm N$_{2}$O in He at 400 °C). In‐situ EXAFS
                      analysis further revealed a crucial role of copper‐ceria
                      interface in this catalytic reaction. We observed dynamic
                      changes in average number of Cu‐Ce scatters under reaction
                      conditions, indicating an enlarging the interface between
                      both copper and ceria phases, where electron and oxygen
                      transfer occurs.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20180898
                      EC (I-20180898-EC) / FS-Proposal: I-20160044 EC
                      (I-20160044-EC) / CALIPSOplus - Convenient Access to Light
                      Sources Open to Innovation, Science and to the World
                      (730872)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20180898-EC /
                      G:(DE-H253)I-20160044-EC / G:(EU-Grant)730872},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000616562900001},
      doi          = {10.1002/cctc.202001829},
      url          = {https://bib-pubdb1.desy.de/record/454742},
}