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@ARTICLE{Heywood:454613,
      author       = {Heywood, Victoria L. and Alford, Thomas P. J. and
                      Roeleveld, Julius J. and Lekanne Deprez, Siebe J. and
                      Verhoofstad, Abraham and van der Vlugt, Jarl Ivar and
                      Domingos, Sérgio R. and Schnell, Melanie and Davis, Anthony
                      P. and Mooibroek, Tiddo J.},
      title        = {{O}bservations of tetrel bonding between $sp^{3}$-carbon
                      and {THF}},
      journal      = {Chemical science},
      volume       = {11},
      number       = {20},
      issn         = {2041-6539},
      address      = {Cambridge},
      publisher    = {RSC},
      reportid     = {PUBDB-2021-00615},
      pages        = {5289 - 5293},
      year         = {2020},
      abstract     = {We report the direct observation of tetrel bonding
                      interactions between $sp^{3}$-carbons of the supramolecular
                      synthon 3,3-dimethyl-tetracyanocyclopropane (1) and
                      tetrahydrofuran in the gas and crystalline phase. The
                      intermolecular contact is established via σ-holes and is
                      driven mainly by electrostatic forces. The complex manifests
                      distinct binding geometries when captured in the crystalline
                      phase and in the gas phase. We elucidate these binding
                      trends using complementary gas phase quantum chemical
                      calculations and find a total binding energy of −11.2 kcal
                      mol$^{−1}$ for the adduct. Our observations pave the way
                      for novel strategies to engineer $sp^{3}$-C centred
                      non-covalent bonding schemes for supramolecular chemistry.},
      cin          = {CFEL-SDCCM / FS-SMP},
      ddc          = {540},
      cid          = {I:(DE-H253)CFEL-SDCCM-20160915 /
                      I:(DE-H253)FS-SMP-20171124},
      pnm          = {6211 - Extreme States of Matter: From Cold Ions to Hot
                      Plasmas (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6211},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34122986},
      UT           = {WOS:000537133000015},
      doi          = {10.1039/D0SC01559H},
      url          = {https://bib-pubdb1.desy.de/record/454613},
}