% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Zhang:454441,
      author       = {Zhang, Zhaoming and Spiers, Kathryn and Vance, Eric R. and
                      Davis, Joel},
      title        = {{P}artitioning of {C}e, as a simulant for {P}u, in a
                      multiphase ceramic nuclear waste form},
      journal      = {Journal of the American Ceramic Society},
      volume       = {103},
      number       = {10},
      issn         = {1551-2916},
      address      = {Westerville, Ohio},
      publisher    = {Soc.},
      reportid     = {PUBDB-2021-00515},
      pages        = {5515 - 5524},
      year         = {2020},
      note         = {Waiting for fulltext},
      abstract     = {A pyrochlore‐rich multiphase ceramic waste form was
                      prepared by the alkoxide‐route and consolidated by
                      sintering in air. Cerium (Ce) was used as a surrogate for
                      plutonium (Pu), which was found in both the major pyrochlore
                      and minor perovskite phases, but not the minor rutile phase.
                      A synchrotron‐based fluorescence X‐ray absorption
                      near‐edge spectroscopy (XANES) imaging technique was
                      employed to determine the Ce oxidation state in each of the
                      two Ce‐containing phases. It was shown that the major
                      pyrochlore phase contains only tetravalent Ce, whereas the
                      minor perovskite phase incorporates exclusively trivalent
                      Ce. The effect of sintering atmosphere was also
                      investigated, which revealed a very different phase
                      assemblage when sintered in argon (Ar). A major perovskite
                      phase was produced under Ar with a minor zirconolite‐4M
                      phase, both containing trivalent Ce. The composition of the
                      minor rutile phase remained the same whether it was sintered
                      in air or Ar. The results demonstrate the importance of
                      controlling the oxidation state of multivalent waste ions in
                      the design of ceramic waste forms.},
      cin          = {FS-PET-S},
      ddc          = {660},
      cid          = {I:(DE-H253)FS-PET-S-20190712},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-MLZ)External-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000538886700001},
      doi          = {10.1111/jace.17277},
      url          = {https://bib-pubdb1.desy.de/record/454441},
}