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@ARTICLE{Altin:454098,
author = {Altin, Serdar and Demirel, S. and OZ, E. and Altin, E. and
Hetherington, C. and Bayri, A. and Avci, Sevda},
title = {{S}ynthesis of {N}a$_{2}${T}i$_{3}${O}$_{7}$ nanorods by a
{V}-assisted route and investigation of their battery
performance},
journal = {CrystEngComm},
volume = {22},
number = {14},
issn = {1466-8033},
address = {London},
publisher = {RSC},
reportid = {PUBDB-2021-00429},
pages = {2483 - 2490},
year = {2020},
abstract = {We report the V-assisted synthesis of Na$_2$Ti$_3$O$_7$
nanorods via a conventional solid state reaction technique.
Energy dispersive X-ray spectroscopy (EDS) mapping showed
that V-ions are not incorporated into the main structure of
the nanorods but rather V behaves as a flux agent during the
growth of the nanorods. The cyclic voltammetry (CV) analysis
of the samples shows changes in the redox peaks as a
function of V content. Our detailed ex situ X-ray
diffraction (XRD), Raman spectroscopy, scanning electron
microscopy (SEM), transmission electron microscopy (TEM) and
X-ray absorption spectroscopy (XAS) analyses after 1000
cycles show that the degradation mechanism is the formation
of various titanium oxide impurity phases which inhibits the
Na-ion diffusion.},
cin = {DOOR ; HAS-User},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {6G3 - PETRA III (POF3-622) / SWEDEN-DESY - SWEDEN-DESY
Collaboration $(2020_Join2-SWEDEN-DESY)$ /
$NFFA-Europe_supported$ - Technically supported by
Nanoscience Foundries and Fine Analysis Europe
$(2020_Join2-NFFA-Europe_funded)$},
pid = {G:(DE-HGF)POF3-6G3 / $G:(DE-HGF)2020_Join2-SWEDEN-DESY$ /
$G:(DE-HGF)2020_Join2-NFFA-Europe_funded$},
experiment = {EXP:(DE-H253)P-P64-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000527016600008},
doi = {10.1039/C9CE01955C},
url = {https://bib-pubdb1.desy.de/record/454098},
}