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@ARTICLE{Jiang:454010,
author = {Jiang, Xinyu and Kim, Hongwon and Deimel, Peter S. and
Chen, Wei and Cao, Wei and Yang, Dan and Yin, Shanshan and
Schaffrinna, Roy and Allegretti, Francesco and Barth,
Johannes V. and Schwager, Martina and Tang, Haodong and
Wang, Kai and Schwartzkopf, Matthias and Roth, Stephan V.
and Müller-Buschbaum, Peter},
title = {{I}nternal nanoscale architecture and charge carrier
dynamics of wide bandgap non-fullerene bulk heterojunction
active layers in organic solar cells},
journal = {Journal of materials chemistry / A},
volume = {8},
number = {44},
issn = {2050-7496},
address = {London [u.a.]},
publisher = {RSC},
reportid = {PUBDB-2021-00367},
pages = {23628 - 23636},
year = {2020},
note = {Waiting for fulltext},
abstract = {Bulk heterojunction (BHJ) organic solar cells have gained
increasing attention in the past few years. In this work,
active layers of a wide-bandgap polymer donor with
benzodithiophene units PBDB-T-2F and a non-fullerene small
molecule acceptor IT-M are assembled into photovoltaic
devices with different amounts of solvent additive
1,8-diiodooctane (DIO). The influence of DIO on the
nanoscale film morphology and crystalline structure as well
as the charge carrier dynamics of the active layers are
investigated by combining grazing-incidence small-angle
X-ray scattering (GISAXS), grazing-incidence wide-angle
X-ray scattering (GIWAXS), X-ray reflectivity (XRR),
UV-visible (UV-vis) absorption spectroscopy, X-ray
photoelectron spectroscopy (XPS), time-resolved
photoluminescence (TRPL) and space charge limited current
measurements, which are correlated with the corresponding
performance of the solar cells. At 0.5 $vol\%$ DIO addition,
the wide-bandgap non-fullerene organic solar cells show the
best performance due to high open-circuit voltage and
short-circuit current resulting from an improved charge
carrier management due to the optimal inner nanoscale
morphology of the active layers in terms of surface
enrichment, crystallinity and crystalline orientation.},
cin = {DOOR ; HAS-User / FS-PET-D},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PET-D-20190712},
pnm = {6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G3 - PETRA III (POF3-622) /
SWEDEN-DESY - SWEDEN-DESY Collaboration
$(2020_Join2-SWEDEN-DESY)$ / DFG project 390776260 - EXC
2089: e-conversion (390776260)},
pid = {G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G3 /
$G:(DE-HGF)2020_Join2-SWEDEN-DESY$ / G:(GEPRIS)390776260},
experiment = {EXP:(DE-H253)P-P03-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000590158400044},
doi = {10.1039/D0TA09671G},
url = {https://bib-pubdb1.desy.de/record/454010},
}