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@ARTICLE{Djinovi:453853,
      author       = {Djinović, Petar and Ristić, Alenka and Žumbar, Tadej and
                      Dasireddy, Venkata D. B. C. and Rangus, Mojca and Dražić,
                      Goran and Popova, Margarita and Likozar, Blaž and Zabukovec
                      Logar, Nataša and Novak Tušar, Nataša},
      title        = {{S}ynergistic effect of {C}u{O} nanocrystals and
                      {C}u-oxo-{F}e clusters on silica support in promotion of
                      total catalytic oxidation of toluene as a model volatile
                      organic air pollutant},
      journal      = {Applied catalysis / B},
      volume       = {268},
      issn         = {0926-3373},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2021-00217},
      pages        = {118749},
      year         = {2020},
      abstract     = {Monometallic (CuO and FeO$_x$) and bimetallic (CuFeO$_x$)
                      entities on different supports are promising
                      transition-metal low-cost catalysts for catalytic oxidation
                      of volatile organic compounds (VOC) from industrial air
                      alternatively to noble-metal catalysts which are currently
                      in use. In this work we report for the first time that the
                      promotion of catalytic oxidation of toluene as a model VOC
                      is due to the cooperative redox effect between CuO
                      nanocrystals and finely dispersed Cu-oxo-Fe clusters on
                      mesoporous silica with defined Fe/Cu molar ratio. This
                      increases the number and reactivity of adsorbed
                      electrophilic (O$^−$ and O$_2^−$) as well as
                      nucleophilic lattice oxygen (O$^{2-}$) species at the CuO
                      crystal and and Cu-oxo-Fe cluster interface, thus providing
                      up to twofold enhancement in catalytic activity for total
                      oxidation of toluene. Catalysts were prepared via direct
                      synthesis of Fe-functionalized disordered mesoporous silica
                      containing only isolated iron sites followed by copper
                      addition via impregnation.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {899 - ohne Topic (POF3-899)},
      pid          = {G:(DE-HGF)POF3-899},
      experiment   = {EXP:(DE-H253)D-C-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000521513300024},
      doi          = {10.1016/j.apcatb.2020.118749},
      url          = {https://bib-pubdb1.desy.de/record/453853},
}