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000453853 1001_ $$0P:(DE-H253)PIP1085891$$aDjinović, Petar$$b0
000453853 245__ $$aSynergistic effect of CuO nanocrystals and Cu-oxo-Fe clusters on silica support in promotion of total catalytic oxidation of toluene as a model volatile organic air pollutant
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000453853 520__ $$aMonometallic (CuO and FeO$_x$) and bimetallic (CuFeO$_x$) entities on different supports are promising transition-metal low-cost catalysts for catalytic oxidation of volatile organic compounds (VOC) from industrial air alternatively to noble-metal catalysts which are currently in use. In this work we report for the first time that the promotion of catalytic oxidation of toluene as a model VOC is due to the cooperative redox effect between CuO nanocrystals and finely dispersed Cu-oxo-Fe clusters on mesoporous silica with defined Fe/Cu molar ratio. This increases the number and reactivity of adsorbed electrophilic (O$^−$ and O$_2^−$) as well as nucleophilic lattice oxygen (O$^{2-}$) species at the CuO crystal and and Cu-oxo-Fe cluster interface, thus providing up to twofold enhancement in catalytic activity for total oxidation of toluene. Catalysts were prepared via direct synthesis of Fe-functionalized disordered mesoporous silica containing only isolated iron sites followed by copper addition via impregnation.
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000453853 7001_ $$0P:(DE-HGF)0$$aRistić, Alenka$$b1
000453853 7001_ $$0P:(DE-HGF)0$$aŽumbar, Tadej$$b2
000453853 7001_ $$00000-0002-0665-7850$$aDasireddy, Venkata D. B. C.$$b3
000453853 7001_ $$0P:(DE-H253)PIP1008433$$aRangus, Mojca$$b4
000453853 7001_ $$0P:(DE-HGF)0$$aDražić, Goran$$b5
000453853 7001_ $$0P:(DE-HGF)0$$aPopova, Margarita$$b6
000453853 7001_ $$0P:(DE-HGF)0$$aLikozar, Blaž$$b7
000453853 7001_ $$0P:(DE-HGF)0$$aZabukovec Logar, Nataša$$b8
000453853 7001_ $$0P:(DE-H253)PIP1010682$$aNovak Tušar, Nataša$$b9$$eCorresponding author
000453853 773__ $$0PERI:(DE-600)2017331-3$$a10.1016/j.apcatb.2020.118749$$gVol. 268, p. 118749 -$$p118749$$tApplied catalysis / B$$v268$$x0926-3373$$y2020
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