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| Home > Publications database > Study of the thermochromic phase transition in CuMo$_{1−x}$W$_x$O$_4$ solid solutions at the W L$_3$-edge by resonant X-ray emission spectroscopy > print |
| 001 | 453510 | ||
| 005 | 20250724175230.0 | ||
| 024 | 7 | _ | |a 10.1016/j.actamat.2020.116581 |2 doi |
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| 100 | 1 | _ | |a Pudza, Inga |0 P:(DE-H253)PIP1029767 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Study of the thermochromic phase transition in CuMo$_{1−x}$W$_x$O$_4$ solid solutions at the W L$_3$-edge by resonant X-ray emission spectroscopy |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2021 |b Elsevier Science |
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| 520 | _ | _ | |a Polycrystalline CuMo$_{1-x}$W$_x$O$_4$ solid solutions were studied by resonant X-ray emission spectroscopy (RXES) at the W L$_3$-edge to follow a variation of the tungsten local atomic and electronic structures across thermochromic phase transition as a function of sample composition and temperature. The experimental results were interpreted using ab initio calculations. The crystal-field splitting parameter Delta for the 5d(W)-states was obtained from the analysis of the RXES plane and was used to evaluate the coordination of tungsten atoms. Temperature-dependent RXES measurements were successfully employed to determine the hysteretic behaviour of the structural phase transition between the alpha and gamma phases in CuMo$_{1-x}$W$_x$O$_4$ solid solutions on cooling and heating, even at low (x<0.10) tungsten content. It was found that tungsten ions have octahedral coordination for in the whole studied temperature range (90-420 K), whereas their coordination changes from tetrahedral to octahedral upon cooling for smaller (x<=0.15) tungsten content. Nevertheless, some amount of tungsten ions was found to co-exists in the octahedral environment at room temperature for x<0.15. The obtained results correlate well with the color change in these solid solutions. |
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| 700 | 1 | _ | |a Kuzmin, Aleksejs |0 P:(DE-H253)PIP1009042 |b 3 |e Corresponding author |
| 773 | _ | _ | |a 10.1016/j.actamat.2020.116581 |g Vol. 205, p. 116581 - |0 PERI:(DE-600)2014621-8 |p 116581 (1-32) |t Acta materialia |v 205 |y 2021 |x 1359-6454 |
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